Extraction from copper pyrites:
Extraction of copper from copper pyrites includes the steps shown below:1. Crushing and concentration:
The ore is first crushed and then concentrated by froth-floatation procedure.
2. Roasting:
The concentrated ore is heated strongly in reverberatory furnace, in the excess of air. During roasting,
i) Moisture is eliminated.ii) The volatile impurities are eliminated.iii) Phosphorus, Sulphur, arsenic and antimony that are present as impurity are eliminated as volatile oxides.S + O2 → SO2P4 + 5O2 → 2P2O54As + 3O2 → 2As2O3iv) The copper pyrite is partially transformed into sulphides of copper and iron.
2CuFeS2 + O2 → Cu2S + 2FeS + SO22FeS + 3O2 → 2FeO + 2SO23. Smelting:
The roasted ore is mix with powdered coke and sand and then heated in a blast furnace. It is made up of steel plates lined within with fire clay bricks. Hot air at 800°C is introduced from the tuyers close to the base of the furnace. As an outcome, the following changes take place.2FeS + 3O2 → 2FeO + 2SO2FeO + SiO2 → FeSiO3 (fusible slag)2Cu2S+ 3O2→ 2Cu2O + 2SO2Cu2O + FeS → Cu2S + FeOFeO + SiO2 → FeSiO3 (fusible slag)As an outcome of smelting, two separate molten layers are generated at the bottom of the furnace. The upper layer comprises of slag and is eliminated as a waste whereas the lower layer is termed as matte. It mainly consists of cuprous sulphide and few unchanged ferrous sulphide.4. Bessemerisation:
The molten matte is transferred to a Bessemer converter. The Bessemer is mounted on horizontal axis and is fitted with small pipes termed as tuyeres via which a blast of hot air and fine sand is entered.
Any arsenic, sulphur, and antimony yet present escape as their respective oxides. Ferrous sulphide present in matte is oxidised into ferrous oxide that joins with silica to form slag.
2FeS + 3O2 → 2FeO + 2SO2FeO + SiO2 → FeSiO3 (slag)A few of the cuprous sulphide undergoes oxidation to form cuprous oxide which then reacts with additional cuprous sulphide to provide copper metal. The impure metal so obtained is termed as blister copper and is around 98% pure.
2Cu2S + 3O2 → 2Cu2O + 2SO22Cu2O + Cu2S → 6Cu + SO25. Refining:
Blister copper has around 2% of impurities and it is purified by electrolytic refining.Electrolytic Refining:
This technique is used to acquire metal of high degree of purity. For electrolytic refining of copper,
i) A block of impure copper metal performs as anode.ii) A thin plate of pure copper metal performs as cathode.iii) Copper sulphate solution acidified with sulphuric acid is carried as electrolyte.Whenever electric current is passed via the electrolytic solution pure copper get deposited on the cathode, impurities settle close to the anode in the form of sludge termed as anode mud.
Latest technology based Chemistry Online Tutoring Assistance
Tutors, at the www.tutorsglobe.com, take pledge to provide full satisfaction and assurance in D Block Elements homework help via online tutoring. Students are getting 100% satisfaction by online tutors across the globe. Here you can get homework help for D Block Elements, project ideas and tutorials. We provide email based D Block Elements homework help. You can join us to ask queries 24x7 with live, experienced and qualified online tutors specialized in D Block Elements. Through Online Tutoring, you would be able to complete your homework or assignments at your home. Tutors at the TutorsGlobe are committed to provide the best quality online tutoring assistance for Inorganic-Chemistry Homework Help and assignment help services. They use their experience, as they have solved thousands of the Chemistry assignments, which may help you to solve your complex issues of D Block Elements. TutorsGlobe assure for the best quality compliance to your homework. Compromise with quality is not in our dictionary. If we feel that we are not able to provide the homework help as per the deadline or given instruction by the student, we refund the money of the student without any delay.
tutorsglobe.com dentrification assignment help-homework help by online nitrogen cycle tutors
tutorsglobe.com seepage pit-construction assignment help-homework help by online rain water harvesting tutors
tutorsglobe.com laboratory diagnosis of diphtheria assignment help-homework help by online corynebacterium diphtheria tutors
tutorsglobe.com derivation of m-m equation assignment help-homework help by online enzyme kinetics tutors
tutorsglobe.com deflation assignment help-homework help by online inflation and deflation tutors
tutorsglobe.com third law of lamarckism assignment help-homework help by online lamarckism tutors
www.tutorsglobe.com offers Stepwise Refinement homework help, assignment help, case study, writing homework help, online tutoring assistance by computer science tutors.
a half duplex system gives for communications in both of the directions, but only in one direction at a time but not simultaneously in both of the direction.
tutorsglobe.com second law of lamarckism assignment help-homework help by online lamarckism tutors
the magnetic field tutorial all along with the key concepts of fields due to magnets, electric field to define magnetic field, field due to currents, force on a current in a magnetic field, magnetic flux density, torque on a rectangular coil and biot-savart law
tutorsglobe.com palmately compound leaf assignment help-homework help by online simple and compound leaves tutors
tutorsglobe.com criticism of says law assignment help-homework help by online says law of market tutors
tutorsglobe.com life cycle of a phage assignment help-homework help by online viruses tutors
alkanols-classification-sources-uses of alkanols tutorial all along with the key concepts of classification of alkanols, sources of alkanols, manufacture of alkanols and uses of ethanol
atomic absorption spectroscopy tutorial all along with the key concepts of preparation of calibration curve, uses of atomic absorption spectroscopy, determination of concentration of magnesium in tap water
1948080
Questions Asked
3689
Tutors
1473573
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!