The Huckel Rule Homework Help - K-12 Grade Level, College Level Chemistry

Aromaticity - The Huckel Rule Homework Help - K-12 Grade Level, College Level Chemistry

Introduction to Hückel's rule

The Hückel's rule estimates whether a planar ring molecule will have aromatic properties or not, in organic chemistry. For its formulation quantum mechanical basis was first worked out by physical chemist that is Erich Hückel in year 1931. The succinct expression as 4n+2 rules has been attributed to von Doering (1951), even though several authors were using this form around on the same time.

Hückel's rule is followed by the Cyclic ring molecule, when the number of its π-electrons equivalent to the 4n+2 where n is zero or any positive integer, even though clear-cut instances are really only established for values of n = 0 up to about n = 6. On the calculations that are using Hückel method Hückel's rule was based, even though it can also be justified by considering a particle in a ring system, by the LCAO- linear combination of atomic orbitals or LCAO is quantum superposition of atomic orbitals and in quantum chemistry it is a method for calculating molecular orbitals. Like a wave functions in the quantum mechanics, electron configurations of the atoms are explained. In the mathematical sense, these wave functions are the basis set of functions, basis functions, which demonstrated the electrons of a given atom. Orbital wave functions are modified in the chemical reactions that are the electron cloud shape is changed, according to type of atoms participating in the chemical bond. Method and by the Pariser-Parr-Pople method.

Than theoretically predicted by alkene hydrogenation data, the Aromatic compounds are more stable; "extra" stability is because of the delocalized cloud of electrons called resonance energy. The Criteria for simple aromatics are:

Follow Huckel's rule, having 4n+2 electrons in delocalized and conjugated p-orbital cloud;

Be able to be planar and are cyclic;

In delocalizing the electrons every atom in circle is capable to participate, by having a p-orbital or an unshared pair of electrons.


The Hückel's rule is not valid for several compounds that are containing more than 3 fused aromatic nuclei in a cyclic fashion. For an instance, 16 conjugated electrons (8 bonds) are contained by the pyrene, and 24 conjugated electrons (12 bonds) are contained by the coronene. Both of these polycyclic molecules are aromatic although they fail 4n+2 rule. Indeed, the Hückel's rule can only be theoretically/ hypothetically acceptable for monocyclic systems.

Three-dimensional rule

Andreas Hirsch and co-workers in Erlangen and Germany in 2000 formulated a rule to determine when a fullerene would be aromatic. They found that fullerene would display aromatic properties when there were 2(n+1)2 π-electrons. This is follows from the fact that an aromatic fullerene must have full icosahedra (or other appropriate) symmetry, so molecular orbitals must be absolutely filled. If there are exactly 2(n+1)2 electrons this is possible, where n is nonnegative integer. Specifically, for an instance, buckminsterfullerene, with 60 π-electrons, is the non-aromatic, since the 60/2 = 30, which is not a perfect square.

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