--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Solubility of a gas The solubility of a

    The solubility of a gas in water depends on: (a) Nature of the gas (b) Temperature (c) Pressure of the gas (d) All of the above. Can someone help me in finding out the right answer.

    		•
  • Q : Symmetry Elements The symmetry of the

    The symmetry of the molecules can be described in terms of electrons of symmetry and the corresponding symmetry operations.Clearly some molecules, like H2O and CH4, are symmetric. Now w

    		•
  • Q : Problem on vapour pressure Choose the

    Choose the right answer from following. If P and P are the vapour pressure of a solvent and its solution respectively N1 and N2 and are the mole fractions of the solvent and solute respectively, then correct relation is: (a) P= PoN1 (b) P= Po N2 (c)P0= N2 (d)

    		•
  • Q : Chem Explain how dissolving the Group

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.

    		•
  • Q : Atmospheric pressure Give me answer of

    Give me answer of this question. The atmospheric pressure is sum of the: (a) Pressure of the biomolecules (b) Vapour pressure of atmospheric constituents (c) Vapour pressure of chemicals and vapour pressure of volatile (d) Pressure created on to atmospheric molecules

    		•
  • Q : Question based on vapour pressure While

    While a substance is dissolved in a solvent, the vapour pressure of the solvent is decreased. This results in: (a) An increase in the boiling point of the solution (b) A decrease in the boiling point of solvent (c) The solution having a higher freezing point than

    		•
  • Q : Molecular Diameters The excluded volume

    The excluded volume b, introduced by vander Wall's as an empirical correction term, can be related to the size gas molecules. To do so, we assume the excluded volume is the result of the pairwise coming together of molecules. This assumption is justified when b values

    		•
  • Q : Reactivity of allyl and benzyl halides

    why allyl halide and haloarenes are more reactive than alkyl halide towards nucleophilic substitution

    		•
  • Q : Describe Transformation Matrices. Each

    Each symmetry operation can be represented by a transformation matrix.You have seen what happens when a molecule is subjected to the symmetry operation that corresponds to any of the symmetry elements of the point group to which the molecule belongs. The m

    		•
  • Q : Molarity of Nacl solution When 5.85 g

    When 5.85 g of NaCl (having molecular weight 58.5) is dissolved in water and the solution is prepared to 0.5 litres, the molarity of the solution is: (i) 0.2 (ii) 0.4 (iii) 1.0 (iv) 0.1

    		•