--%>

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Organic structure of cetearyl alcohol

    Can we demonstration the organic structure of cetearyl alcohol and state me what organic family it is?

  • Q : Analytical chemistry 37% weight of HCl

    37% weight of HCl and density is 1.1g/ml. find molarity of HCl

  • Q : Vapour pressure over mercury Choose the

    Choose the right answer from following. At 300 K, when a solute is added to a solvent its vapour pressure over the mercury reduces from 50 mm to 45 mm. The value of mole fraction of solute will be: (a)0.005 (b)0.010 (c)0.100 (d)0.900

  • Q : Concentration factor affected by

    Can someone please help me in getting through this problem. Which of the given concentration factor is affected by the change in temperature: (1) Molarity (2) Molality (3) Mole fraction (4) Weight fraction

  • Q : Composition of the vapour Choose the

    Choose the right answer from following. An ideal solution was obtained by mixing methanol and ethanol. If the partial vapour pressure of methanol and ethanol are 2.619KPa and 4.556KPa respectively, the composition of the vapour (in terms of mole fraction) will be: (

  • Q : Molarity based question Help me to

    Help me to solve this problem. 4.0 gm of NaOH are contained in one decilitre of solution. Its molarity would be: (a) 4 M (b)2 M (c)1 M (d)1.5 M

  • Q : Vapour pressure of volatile substance

    Provide solution of this question. According to Raoult's law the relative lowering of vapour pressure of a solution of volatile substance is equal to: (a) Mole fraction of the solvent (b) Mole fraction of the solute (c) Weight percentage of a solute (d) Weight perc

  • Q : Quantum Mechanical Operators The

    The quantum mechanical methods, illustrated previously by the Schrödinger equation, are extended by the use of operators. Or, w

  • Q : Concentration of an aqueous solution

    Give me answer of this question. The concentration of an aqueous solution of 0.01M CH3OH solution is very nearly equal to which of the following : (a) 0.01%CH3OH (b) 0.1%CH3OH (c) xCH3OH= 0.01 (d) 0.99MH2O (

  • Q : Acid value definition The acid value

    The acid value definition is the number milligrams of KOH needed to neutralize the acid present in one gram oil and fats however why not employ NaOH for the neutralization?