--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Linde liquefaction process Liquefied

    Liquefied natural gas (LNG) is produced using a Linde liquefaction process from pure methane gas at 3 bar and 280 K (conditions at point 1 in figure below). A three-stage compressor with interceding is used to compress the methane to 100 bar (point 2). The first stage

    		•
  • Q : Mole fraction of Carbon dioxide Choose

    Choose the right answer from following. If we take 44g of CO2 and 14g of N2 what will be mole fraction of CO2 in the mixture: (a) 1/5 (b) 1/3 (c) 2/3 (d) 1/4

    		•
  • Q : Relative lowering of vapour pressure

    Which of the following solutions will have a lower vapour pressure and why? a) A 5% aqueous solution of cane sugar. b) A 5% aqueous solution of urea.

    		•
  • Q : Relative reactivity Which is more

    Which is more reactive towards nucleophilic substitution aryl halide or vinyl halides

    		•
  • Q : Question based on lowest vapour pressure

    Give me answer of this question. Among the following substances the lowest vapour pressure is exerted by: (a) Water (b) Mercury (c) Kerosene (d) Rectified spirit

    		•
  • Q : Problem on thermodynamic equilibrium In

    In the manufacture of sulphuric acid by the contact process, S02 is oxidized to SO3 over a vanadium catalyst: The reactor is adiabatic and operates at atmospheric pressure. The gases enter the reactor at 410&d

    		•
  • Q : What is protein in Chemistry Illustrate

    Illustrate what is protein in Chemistry?

    		•
  • Q : Problem on distribution law The

    The distribution law is exerted for the distribution of basic acid among: (i) Water and ethyl alcohol (ii) Water and amyl alcohol (iii) Water and sulphuric acid (iv) Water and liquor ammonia What is the right answer.

    		•
  • Q : Significance of the organic chemistry

    Describe some of the significance of the organic chemistry in brief?

    		•
  • Q : Cations Explain how dissolving the

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.

    		•