--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Problem based on molality of glucose

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

    		•
  • Q : Donnan Membrane Equilibria The electric

    The electric charge acquired by macromolecules affects the equilibrium set up across a semipermeable membrane.Laboratory studies of macromolecule solutions as in osmotic pressure and dialysis studies confine the macromolecules to one compartment while allo

    		•
  • Q : Explain polyhalogen compounds with

    Carbon compounds containing more than one halogen atom are called polyhalogen compounds. Most of these compounds are valuable in industry and agriculture. Some important polyhalogen compounds are described as follows:

    Q : What are lattices and unit cells? The

    The repeating, atomic level structure of a crystal can be represented by a lattice and by the repeating unit of the lattice, the unit cell.It was apparent very early in the study of crystals that the shapes of crystals stem from an ordered array of smaller

    		•
  • Q : Biodegradable polymers what are the

    what are the examples of biodegradable polymers

    		•
  • Q : Explain the preparation of phenols. The

    The methods used for the preparation of phenols are given below:    From aryl sulphonic acids

    		•
  • Q : Problem on vapour pressure and mole

    Provide solution of this question. The vapour pressure of a solvent decreased by 10 mm of mercury, when a non-volatile solute was added to the solvent. The mole fraction of the solute in the solution is 0.2. What should be the mole fraction of the solvent, if decrea

    		•
  • Q : PH of an Alkyl Halide Briefly state the

    Briefly state the pH of an Alkyl Halide?

    		•
  • Q : What are Vander Waal's Radii? Vander

    Vander Waal's radii can be assigned to the atoms of molecules on the basis of the closeness of approach of these atoms in crystalline substances. Diffraction studies of crystals give information about hoe molecules can approach each other and can pack

    		•
  • Q : Number of moles of potassium chloride

    Choose the right answer from following. The number of moles of KCL in 1000ml of 3 molar solution is: (a)1 (b)2 (c)3 (d)1.5

    		•