--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Calculating value of molar solution

    Choose the right answer from following. An X molal solution of a compound in benzene has mole fraction of solute equal to 0.2. The value of X is: (a)14 (b) 3.2 (c) 4 (d) 2

    		•
  • Q : Application of colligative properties

    Choose the right answer from following. Colligative properties are used for the determination of: (a) Molar Mass (b) Equivalent weight (c) Arrangement of molecules (d) Melting point and boiling point (d) Both (a) and (b)  

    		•
  • Q : Problem on partial pressure i) Show

    i) Show that the equilibrium constant Kp for the reaction CaCo3(s) ↔ CaO(s) +CO2(g)is about unity (i.e. = 1.0) at 895 °C.ii) If two grams of calcium carbonate are pl

    		•
  • Q : Which is polar HCl or HF Which one is

    Which one is polar HCl or HF?

    		•
  • Q : Problem on Neutralization What weight

    What weight of hydrated oxalic acid should be added for complete neutralisation of 100 ml of 0.2N - NaOH solution? (a) 0.45 g  (b)0.90 g  (c) 1.08 g  (d) 1.26 g      Answer

    		•
  • Q : Vapour pressure of benzene Give me

    Give me answer of this question. The vapour pressure of benzene at a certain temperature is 640mm of Hg. A non-volatile and non-electrolyte solid weighing 2.175g is added to 39.08g of benzene. The vapour pressure of the solution is 600,mm of Hg . What is the mo

    		•
  • Q : Number of electrons in the benzene

    Describe the number of electrons in the benzene? Write a short note on it?

    		•
  • Q : Difference in Mendeleevs table and

    Briefly describe the difference in the Mendeleev’s table and modern periodic table?

    		•
  • Q : Meaning of molality of a solution The

    The molality of a solution will be: (i) Number of moles of solute per 1000 ml of solvent (ii) Number of moles of solute per 1000 gm of solvent (iii) Number of moles of solute per 1000 ml of solution (iv) Number of gram equivalents of solute per 1000 m

    		•
  • Q : Procedure for separating the components

    Briefly describe the procedure for separating the components of the gun-powder?

    		•