--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Question based on relative lowering of

    Give me answer of this question. When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is equal to: (a) Mole fraction of solute (b) Mole fraction of solvent (c) Concentration of the solute in grams per litre

    		•
  • Q : Calculation of concentration of the

    Choose the right answer from following. 200ml of a solution contains 5.85 dissolved sodium chloride. The concentration of the solution will be(Na= 23: cl = 35.5 ) (a) 1 molar (b) 2 molar (c) 0.5 molar (d) 0.25 molar

    		•
  • Q : Dipole moment of chloro-octane Describe

    Describe the dipole moment of chloro-octane in brief?

    		•
  • Q : Vapour pressure of volatile substance

    Provide solution of this question. According to Raoult's law the relative lowering of vapour pressure of a solution of volatile substance is equal to: (a) Mole fraction of the solvent (b) Mole fraction of the solute (c) Weight percentage of a solute (d) Weight perc

    		•
  • Q : What is ortho effect? Orthosubstituted

    Orthosubstituted anilines are generally weaker bases than aniline irrespective of the electron releasing or electron withdrawing nature of the substituent. This is known as ortho effect and may probably be due to combined electronic and steric factors.The overall basic strength of ort

    		•
  • Q : Question on Mole fraction Mole fraction

    Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of  moles of solute/ Mass of solvent in kg (d) no. of moles of any

    		•
  • Q : Concentration of an aqueous solution

    Give me answer of this question. The concentration of an aqueous solution of 0.01M CH3OH solution is very nearly equal to which of the following : (a) 0.01%CH3OH (b) 0.1%CH3OH (c) xCH3OH= 0.01 (d) 0.99MH2O (

    		•
  • Q : Define the term oxidizing agent Briefly

    Briefly define the term oxidizing agent?

    		•
  • Q : Molecular energies and speeds The

    The average translational kinetic energies and speeds of the molecules of a gas can be calculated.The result that the kinetic energy of 1 mol of the molecules of a gas is equal to 3/2 RT can be used to obtain numerical values for the

    		•
  • Q : Theory of three dimensional motion

    Partition function; that the translational energy of 1 mol of molecules is 3/2 RT will come as no surprise. But the calculation of this result further illustrates the use of quantized states and the partition function to obtain macroscopic properties. The partition fu

    		•