--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Problem on vapor-liquid equilibrium Two

    Two tanks which contain water are connected to each other through a valve. The initial conditions are as shown (at equilibrium): 683_tank question.jpg

    		•
  • Q : Donnan Membrane Equilibria The electric

    The electric charge acquired by macromolecules affects the equilibrium set up across a semipermeable membrane.Laboratory studies of macromolecule solutions as in osmotic pressure and dialysis studies confine the macromolecules to one compartment while allo

    		•
  • Q : Pressure Phase Diagrams The occurrence

    The occurrence of different phases of a one component system can be shown on a pressure temperature. The phases present in a one line system at various temperatures can be conveniently presented on a P- versus-T diagram. An example is pro

    		•
  • Q : Solution density of water is 1g/mL.The

    density of water is 1g/mL.The concentration of water in mol/litre is

    		•
  • Q : What is cannizaro reaction? Explain

    Aldehydes which do not have  -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solutio

    		•
  • Q : Means of molality Give me answer of

    Give me answer of this question. The number of moles of solute per kg of a solvent is called its: (a) Molarity (b) Normality (c) Molar fraction (d) Molality

    		•
  • Q : Composition of the vapour Choose the

    Choose the right answer from following. An ideal solution was obtained by mixing methanol and ethanol. If the partial vapour pressure of methanol and ethanol are 2.619KPa and 4.556KPa respectively, the composition of the vapour (in terms of mole fraction) will be: (

    		•
  • Q : What is depression in freezing point?

    Freezing point of a substance is the temperature at which solid and liquid phases of the substance coexist. It is defined as the temperature at which its solid and liquid phases have the same vapour pressure. The freezing point o

    		•
  • Q : Concentration of urea Help me to go

    Help me to go through this problem. 6.02x 1020 molecules of urea are present in 100 ml of its solution. The concentration of urea solution is: (a) 0.02 M (b) 0.01 M (c) 0.001 M (d) 0.1 M (Avogadro constant, N4= 6.02x 1023mol -1)<

    		•
  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

    		•