--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : What are ion selective electrodes? Ion

    Ion Selective Electrodes An ion selective membrane can be used to form an electrochemical cell whose emf depends on the concentration of that ion. Before we proceed to an important application of emf measurements, brie

    		•
  • Q : What do you mean by the term tripod

    What do you mean by the term tripod? Also state its uses?

    		•
  • Q : Amines arrange in decreasing order of

    arrange in decreasing order of basicity pi pyridine,pyridine,pyrrole, morphine

    		•
  • Q : What are emulsions?Describe its

    Emulsions are colloidal solutions in which disperse phase as well as dispersion medium is both liquids. Emulsions can be broadly classified into two types: (i) Oil in water (O/W type) emulsions: in this type of emulsions, oil acts disperse phase and water acts

    		•
  • Q : F-centres If a electron is present in

    If a electron is present in place of anion in a crystal lattice, then it is termed as: (a) Frenkel defect  (b) Schottky defect  (c) Interstitial defects (d) F-centre Answer: (d) When electrons are trapped in anion vacancies, thes

    		•
  • Q : Molar solution of sulphuric acid Choose

    Choose the right answer from following. The molar solution of sulphuric acid is equal to: (a) N solution (b) 2Nsolution (c) N/2solution (d) 3Nsolution

    		•
  • Q : Neutralisation of phosphorous acids

    Provide solution of this question. To neutralise completely 20 mL of 0.1 M aqueous solution of phosphorous acid (H3 PO3) the volume of 0.1 M aqueous KOH solution required is: (a) 40 mL (b) 20 mL (c) 10 mL (d) 60 mL

    		•
  • Q : Solutions The relative lowering of

    The relative lowering of vapour pressure of 0.2 molal solution in which solvent is benzene

    		•
  • Q : What is electrolytic dissociation? The

    The Debye Huckel theory shows how the potential energy of an ion in solution depends on the ionic strength of the solution.Except at infinite dilution, electrostatic interaction between ions alters the properties of the solution from those excepted from th

    		•
  • Q : Problem on distribution law The

    The distribution law is exerted for the distribution of basic acid among: (i) Water and ethyl alcohol (ii) Water and amyl alcohol (iii) Water and sulphuric acid (iv) Water and liquor ammonia What is the right answer.

    		•