--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : What is cannizaro reaction? Explain

    Aldehydes which do not have  -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solutio

    		•
  • Q : Death cap musrooms the death cap

    the death cap mushroom based on your knowledge of the biochemistry of dna and rna

    		•
  • Q : Hydrocarbons list and identify

    list and identify differences between the major classes of hydrocarbons

    		•
  • Q : Precipitation problem On passing H 2 S 

    On passing H2S  gas through a solution of Cu+ and Zn+2 ions, CuS is precipitated first because: (i) Solubility product of CuS is equal to the ionic product of ZnS (ii) Solubility product of CuS is equal to the solubility product o

    		•
  • Q : How haloalkanes are prepared from

    This is the common method for preparing haloalkanes in laboratory. Alcohols can be converted to haloalkanes by substitution of - OH group with a halogen atom. Different reagents can be used to get haloa

    		•
  • Q : Law of multiple proportions and Law of

    Describe the difference between law of multiple proportions and law of definite proportions?

    		•
  • Q : Infrared Adsorption The adsorption of

    The adsorption of infrared radiation by diatomic molecules increases the vibrational energy fo molecules and gives information about the force constant for the "spring" of the molecule.;The molecular motion that has the next larger energy level spacing aft

    		•
  • Q : Molal elevation constant of water The

    The boiling point of 0.1 molal aqueous solution of urea is 100.18oC  at 1 atm. The molal elevation constant of water is: (a) 1.8    (b) 0.18   (c) 18    (d) 18.6Answer: (a) Kb

    		•
  • Q : Dipole attractions for london dispersion

    Illustrate how are dipole attractions London dispersion forces and hydrogen bonding similar?

    		•
  • Q : Relative lowering of the vapour pressure

    Choose the right answer from following.The relative lowering of the vapour pressure is equal to the ratio between the number of: (a) Solute moleules and solvent molecules (b) Solute molecules and the total molecules in the solution (c) Solvent molecules and the tota

    		•