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Procedure to judge that organic compound is pure or not

Describe briefly the procedure to judge that the given organic compound is pure or not?

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There are many analytical methods to recognize the organic compound is pure or not such as determine the purity through tlc, hptlc, hplc and as well gavimetric techniques are as well there like the limit test and ash of the compound as so forth.   

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    Q : Strength of the Hydrochloric acid

    Provide solution of this question. 1.0 gm of pure calcium carbonate was found to need 50 ml of dilute HCL for complete reaction. The strength of the HCL solution is specified by : (a) 4 N (b) 2 N (c) 0.4 N (d) 0.2 N