--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Electrochemistry ( electrolysis of

    1. Define Faraday's first law of electrolysis 2. define Faraday's second law of electrolysis

    		•
  • Q : Calculate PH value for a acetic acid 1.

    1. A solution of 0.100 M acetic acid is prepared. a) What is its pH value? b) If 20% of the initial acetic acid is converted to the acetate form by titration with NaOH, what is the resultant pH?

    		•
  • Q : Problem on molality Select the right

    Select the right answer of the question. Calculate the molality of 1 litre solution of 93% H2SO4 (weight/volume). The density of the solution is 1.84 g /ml : (a) 10.43 (b) 20.36 (c) 12.05 (d) 14.05

    		•
  • Q : Question 6 A student was analyzing an

    A student was analyzing an unknown containing only Group IV cations. When the unknown was treated with 3M (NH4)2CO3 solution, a white precipitate formed. Because the acetic acid bottle was empty, the student used 6M HCl to dissolve the precipitate. Following the procedure of this experiment, the stu

    		•
  • Q : Finding Active mass of urea Can someone

    Can someone please help me in getting through this problem. 10 litre solution of urea comprises of 240 gm urea. The active mass of urea is: (i) 0.04 (ii) 0.02 (iii) 0.4 (iv) 0.2

    		•
  • Q : Functions of centrioles Describe

    Describe briefly the functions of centrioles?

    		•
  • Q : M ive me answer of this question. When

    ive me answer of this question. When mercuric iodide is added to the aqueous solution of potassium iodide, the: (a) Freezing point is raised (b) Freezing point is lowered (c) Freezing point does not change (d) Boiling point does not change

    		•
  • Q : Vapour pressure Vapour pressure of

    Vapour pressure of methanol in water Give me answer of this question. An aqueous solution of methanol in water has vapour pressure: (a) Equal to that of water (b) Equal to that of methanol (c) More than that of water (d) Less than that of water

    		•
  • Q : Relative lowering of vapour pressure

    explain the process of relative lowering of vapour pressure

    		•
  • Q : What is synthetic rubber and how it

    To meet human needs, scientists have started preparing synthetic rubbers. Besides having similar properties as natural rubbers they are tougher, more flexible and more durable than natural rubber. They are capable of getting stretched to twice its length. Though, it reverts to its original shape

    		•