--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Finding Molarity of final mixture Can

    Can someone help me in finding out the right answer. 25ml of 3.0 MHNO3 are mixed with 75ml of 4.0 MHNO3. If the volumes are adding up the molarnity of the final mixture would be: (a) 3.25M (b) 4.0M (c) 3.75M (d) 3.50M

    		•
  • Q : Q what is the basicity of primary

    what is the basicity of primary secondary and tertiary amines in chlorobenzene

    		•
  • Q : Calculating amount of Sodium hydroxide

    Choose the right answer from following. The amount of NaOH in gms in 250cm3 of a0.100M NaOH solution would be : (a) 4 gm (b) 2 gm (c) 1 gm (d) 2.5 gm

    		•
  • Q : Ddd 4) The addition of S2- ion to

    4) The addition of S2- ion to Fe(OH)2(s). Explain why the addition of S2- ion to Cr(OH)3(s) does not result in the formation of Cr2S3(s).

    		•
  • Q : Water under pressure problem-henry law

    Can someone help me in going through this problem. The statement “When 0.003 moles of a gas are dissolved in 900 gm of water under a pressure of 1 atm, 0.006 moles will be dissolved under the pressure of 2 atm", signfies: (a)

    		•
  • Q : Problem on vapour pressure and mole

    Provide solution of this question. The vapour pressure of a solvent decreased by 10 mm of mercury, when a non-volatile solute was added to the solvent. The mole fraction of the solute in the solution is 0.2. What should be the mole fraction of the solvent, if decrea

    		•
  • Q : Number of moles present in water

    Provide solution of this question. How many moles of water are present in 180 of water: (a)1 mole (b)18 mole (c)10 mole (d)100 mole

    		•
  • Q : Partial vapour pressure of volatile

    Choose the right answer from following. For a solution of volatile liquids the partial vapour pressure of each component in solution is directly proportional to: (a) Molarity (b) Mole fraction (c) Molality (d) Normality

    		•
  • Q : Influence of temperature Can someone

    Can someone please help me in getting through this problem. With increase of temperature, which of the following changes: (i) Molality (ii) Weight fraction of solute (iii) Fraction of solute present in water (iv) Mole fraction.

    		•
  • Q : Numerical The volume of water to be

    The volume of water to be added to 100cm3 of 0.5 N N H2SO4 to get decinormal concentration is : (a) 400 cm3 (b) 500cm3 (c) 450cm3 (d)100cm3

    		•