--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : What is Distillation Separation by

    Separation by distillation can be described with a boiling point diagram. The important process of distillation can now be investigated. From the boiling point diagram one can see that if a small amount of vapour were removed from a liquid of composit

    		•
  • Q : Why acetic has less conductivity than

    Illustrate the reason, why acetic has less conductivity than Hcl?

    		•
  • Q : Problem on normality Help me to solve

    Help me to solve this problem. 0.5 M of H2AO4 is diluted from 1 lire to 10 litre, normality of resulting solution is : (a)1 N (b) 0.1 N (c)10 N (d)11 N

    		•
  • Q : Question on Mole fraction Mole fraction

    Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of  moles of solute/ Mass of solvent in kg (d) no. of moles of any

    		•
  • Q : Problem on volumetric flow rate Methane

    Methane containing 4 mol% N2 is flowing through a pipeline at 105.1 kpa and 22 °C. To check this flow rate, N2 at the same temperature and pressure are introduced to the pipeline at the rate of 2.83 m3/min. At the end of the pipe (

    		•
  • Q : Molecular mass from Raoults law Provide

    Provide solution of this question. Determination of correct molecular mass from Raoult's law is applicable to: (a) An electrolyte in solution (b) A non-electrolyte in a dilute solution (c) A non-electrolyte in a concentrated solution (d) An electrolyte in a liquid so

    		•
  • Q : What are diazonium salts? The diazonium

    The diazonium salts are represented by the general formula ArN2 +X where X- ion may be anion such as (Cl) ¨, B ¨r, HSO

    		•
  • Q : Define thermal energy The thermal part

    The thermal part of the internal energy and the enthalpy of an ideal gas can be given a molecular level explanation. All the earlier development of internal energy and enthalpy has been "thermodynamic". We have made no use o

    		•
  • Q : Decision about dipole moment is present

    How can you decide if there is a dipole moment or not?

    		•
  • Q : Molecular weight of solute Select right

    Select right answer of the question. A dry air is passed through the solution, containing the 10 gm of solute and 90 gm of water and then it pass through pure water. There is the depression in weight of solution wt by 2.5 gm and in weight of pure solvent by 0.05 gm. C

    		•