--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : P block why BiF3 is ionic whereas other

    why BiF3 is ionic whereas other trihalides are covalent in nature?

  • Q : What is Elevation in boiling point? The

    The boiling of a liquid may be defused by the temperature at which its vapour pressure which is equal to atmospheric pressure. The effect of addition in a non-volatile solute on the boiling point shown and its solution containing non-volatile solute with tempe

  • Q : Molecular Structure type The ionic

    The ionic radii of Rb+ and I- respectively are 1.46 Å and 2.16Å. The very most probable type of structure exhibited by it is: (a) CsCl type  (b) ZnS type  (c) Nacl type  (d) CaF2 type

    Q : Question related to molarity Help me to

    Help me to go through this problem. Molarity of a solution containing 1g NaOH in 250ml of solution: (a) 0.1M (b) 1M (c) 0.01M (d) 0.001M

  • Q : Problem on moles of solution The number

    The number of moles of a solute in its solution is 20 and total no. of moles are 80. The mole fraction of solute wil be: (a) 2.5 (b) 0.25 (c) 1 (d) 0.75

  • Q : Moles of chloride ion Select the right

    Select the right answer of the question. A solution of CaCl2 is 0.5 mol litre , then the moles of chloride ion in 500ml will be : (a) 0.25 (b) 0.50 (c) 0.75 (d)1.00

  • Q : Help 1) Chromium(III) hydroxide is

    1) Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer. 2) Explain how dissolving t

  • Q : Explain Solid Compound Formation. In

    In some two component, solid liquid systems, a solid compound forms.In systems in which the components have an interaction for such other, a solid state compound of the two compounds of the two components can form.Formic acid and formaide form a solid state, one-to-one com

  • Q : What are various structure based

    This classification of polymers is based upon how the monomeric units are linked together. Based on their structure, the polymers are classified as: 1. Linear polymers: these are the polymers in which monomeric units are linked together to form long straight c

  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal