--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problem on vapour pressure Choose the

    Choose the right answer from following. If P and P are the vapour pressure of a solvent and its solution respectively N1 and N2 and are the mole fractions of the solvent and solute respectively, then correct relation is: (a) P= PoN1 (b) P= Po N2 (c)P0= N2 (d)

  • Q : Problem on Clausius equation of state

    If a gas can be described by the Clausius equation of state: P (V-b) = RT Where b is a constant, then:  (a) Obtain an expression for the residual vo

  • Q : Haloalkanes define primary secondary

    define primary secondary and tertiary alkyl halides with examples

  • Q : Volume of solution containing solute

    What volume of solution contains 0.1 mole of the solute: (a) 100ml (b) 125ml  (c) 500ml (d) 62.5ml Choose the right answer from above.

  • Q : Why medications include the hcl Why do

    Why do various medications include the hcl? Describe briefly?

  • Q : Describe First Order Rate Equation The

    The integrated forms of the first order rate equations are conveniently used to compare concentration time results with this rate equation. Rate equations show the dependence of the rate of the reaction on concentration can be integrated to give expressions fo

  • Q : Freezing point of equimolal aqueous

    The freezing point of equi-molal aqueous solution will be maximum for:            (a) C6H5NH3+Cl-(aniline hydrochloride)  (b) Ca(NO3

  • Q : Sedimentation and Velocity The first

    The first method begins with a well defined layer, or boundary, of solution near the center of rotation and tracks the movement of this layer to the outside of the cell as a function of time. Such a method is termed a sedimentary velocity experiment. A

  • Q : Ionization Potential Second ionization

    Second ionization potential of Li, Be and B is in the order (a)Li>Be>B (b)Li>B>Be (c)Be>Li>B (d)B>Be>Li

  • Q : Some basic concepts of chemistry an

    an atom of an element is 10.1 times heavier than the mass of a carbon atom.What is its mass in amu?