--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Explain Solid Compound Formation. In

    In some two component, solid liquid systems, a solid compound forms.In systems in which the components have an interaction for such other, a solid state compound of the two compounds of the two components can form.Formic acid and formaide form a solid state, one-to-one com

  • Q : Problem on physical and thermodynamic

    The shells of marine organisms contain calcium carbonate CaCO3, largely in a crystalline form known as calcite. There is a second crystalline form of calcium carbonate known as aragonite. Physical and thermodynamic properties of calcite and aragonite at 298

  • Q : F-centres If a electron is present in

    If a electron is present in place of anion in a crystal lattice, then it is termed as: (a) Frenkel defect  (b) Schottky defect  (c) Interstitial defects (d) F-centre Answer: (d) When electrons are trapped in anion vacancies, thes

  • Q : Dipole moment Elaborate a dipole moment

    Elaborate a dipole moment?

  • Q : What are methods of phenol preparation

    Phenol was initially obtained by fractional distillation of coal

  • Q : How reactive is Trimethylindium towards

    Illustrate the reason, how reactive is Trimethylindium towards oxygen and water?

  • Q : Problem on colligative properties

    Choose the right answer from following. The magnitude of colligative properties in all colloidal dispersions is : (a) Lowerthan solution (b)Higher than solution(c) Both (d) None

  • Q : Vapour pressure of water Give me answer

    Give me answer of this question. 5cm3 of acetone is added to 100cm3 of water, the vapour pressure of water over the solution: (a) It will be equal to the vapour pressure of pure water (b) It will be less than the vapour pressure of pure water

  • Q : Lowering of vapour pressure Help me to

    Help me to go through this problem. Lowering of vapour pressure is highest for: (a) urea (b) 0.1 M glucose (c) 0.1M MgSo4 (d) 0.1M BaCl2

  • Q : Effect on vapour pressure of dissolving

    Give me answer of this question. When a substance is dissolved in a solvent the vapour pressure of the solvent is decreased. This results in: (a) An increase in the b.p. of the solution (b) A decrease in the b.p. of the solvent (c) The solution having a higher fr