--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problem on Molar solution Can someone

    Can someone please help me in getting through this problem. 2.0 molar solution is acquired, when 0.5 mole solute is dissolved in: (i) 250 ml solvent (ii) 250 g solvent (iii) 250 ml solution (iv) 1000 ml solvent

  • Q : Describe the function of the

    Briefly describe the function of the monosaccharide?

  • Q : Electrons present in a benzene How

    How many electrons are present in a benzene?

  • Q : Define Virial Equation The constant of

    The constant of vander Waal's equation can be related to the coefficients of the virial equation.  Vander Waal's equation provides a good overall description of the real gas PVT behaviour. Now let us

  • Q : How alkyl group reactions takes place?

    Halogenations: ethers react with chlorine and bromine to give substitution products. The extent of halogenations depends upon the conditions of reacti

  • Q : Volume of solution containing solute

    What volume of solution contains 0.1 mole of the solute: (a) 100ml (b) 125ml  (c) 500ml (d) 62.5ml Choose the right answer from above.

  • Q : Explain vapour pressure of liquid

    Liquid solutions are obtained when the solvent is liquid. The solute can be a gas, liquid or a solid. In this section we will discuss the liquid solutions containing solid or liquid solutes. In such solutions the solute may or may not be volatile. We shall limit our d

  • Q : Simulate the column in HYSYS The

    The objective of this work is to separate a binary mixture and to cool down the bottom product for storage. (Check table below to see which mixture you are asked to study). 100 kmol of feed containing 10 mol percent of the lighter component enters a continuous distillation column at the m

  • Q : What are aliphatic amines and its

    In common system, the aliphatic amines are named by using prefix for alkyl group followed by the word amine.In case of mixed amines, the name of alkyl groups are arranged in alphabetical order. This is followed by the word amine. However, for simple secondary or tertiary amines anothe

  • Q : Help 1) Chromium(III) hydroxide is

    1) Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer. 2) Explain how dissolving t