--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Calculating Formulae Superphosphate has

    Superphosphate has the formula CaH4(PO4)2 H2O, what is the calculation to get the percentage of Phosphorus, I need to show the calculation. I know it is 30.9737622 u in weight and 2 atoms of the formula, but not sure how to work the calculation backwards.

    		•
  • Q : Volume hydrogen peroxide Choose the

    Choose the right answer from following. The normality of 10 lit. volume hydrogen peroxide is: (a) 0.176 (b) 3.52 (c) 1.78 (d) 0.88 (e)17.8

    		•
  • Q : Molecular energies and speeds The

    The average translational kinetic energies and speeds of the molecules of a gas can be calculated.The result that the kinetic energy of 1 mol of the molecules of a gas is equal to 3/2 RT can be used to obtain numerical values for the

    		•
  • Q : What is covalent radii? Explain its

    Average covalent radii can be assigned on the basis of molecular structures. The accumulation of structural data by spectroscopic studies and both electron and x-ray diffraction studies allows one to investigate the possibili

    		•
  • Q : Sugar solution The solution of sugar in

    The solution of sugar in water comprises: (i) Free atoms (ii) Free ions (iii) Free molecules (iv) Free atom and molecules. Choose the right answer from the above.

    		•
  • Q : Molar concentration of Iron chloride

    Provide solution of this question. A certain aqueous solution of FeCl3 (formula mass =162) has a density of 1.1g/ml and contains 20.0% Fecl. Molar concentration of this solution is: (a) .028 (b) 0.163 (c) 1.27 (d) 1.47

    		•
  • Q : Precipitation Addition of conc. HCl to

    Addition of conc. HCl to saturated Bacl2 solution precipitates Bacl2 ; because of the following reason : (a) It follows from Le Chatelier's principle (b) Of common-ion effect (c) Ionic product (Ba++)(cl) remains constant in a saturated sol

    		•
  • Q : Molarity of sodium hydroxide Can

    Can someone please help me in getting through this problem. Determine the molarity of a solution having 5g of sodium hydroxide in 250ml  solution is: (i) 0.5  (ii) 1.0  (iii) 2.0   (d) 0.1Answer: The right answer i

    		•
  • Q : Neutralization of benzoic acid Choose

    Choose the right answer from following. How many grams of NaOH will be required to neutralize 12.2 grams of benzoic acid : (a) 40gms (b) 4gms (c)16gms (d)12.2gms

    		•
  • Q : Modes of concentration Which of the

    Which of the given modes of expressing concentration is fully independent of temperature: (1) Molarity (2) Molality (3) Formality (4) Normality Choose the right answer from above.

    		•