--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Explain Polyatomic Vibrational Spectra

    Polyatomic molecules vibrate in a number of ways, and some of these vibrations can be studied by infrared absorption spectroscopy and some by Raman spectroscopy. The characters of transformation matrices for all 3n translation rotation vibration motio

  • Q : Calculating weight of acid Give me

    Give me answer of this question. The formula weight of H2SO4 is 98. The weight of the acid in 400mi of solution is: (a)2.45g (b) 3.92g (c) 4.90g (d) 9.8g

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : Dependcy of colligative properties

    Colligative properties of a solution depends upon: (a) Nature of both solvent and solute (b) The relative number of solute and solvent particles (c) Nature of solute only (d) Nature of solvent only

  • Q : What do you mean by the term medicine

    What do you mean by the term medicine dropper? Explain briefly?

  • Q : Donnan Membrane Equilibria The electric

    The electric charge acquired by macromolecules affects the equilibrium set up across a semipermeable membrane.Laboratory studies of macromolecule solutions as in osmotic pressure and dialysis studies confine the macromolecules to one compartment while allo

  • Q : Problem on endothermic or exothermic At

    At low temperatures, mixtures of water and methane can form a hydrate (i.e. a solid containing trapped methane). Hydrates are potentially a very large source of underground trapped methane in the pole regions but are a nuisance when they form in pipelines and block th

  • Q : Various cons of eating the organic foods

    Describe the various cons of eating the organic foods? Briefly illustrate it.

  • Q : Thermodynamics 1 Lab Report I already

    I already did Materials and Methods section. I uploaded it with the instructions. Also, make sure to see Concept Questions and Thinking Ahead in the instructions that I uploaded. deadline is tomorow at 8 am

  • Q : Sedimentation and Velocity The first

    The first method begins with a well defined layer, or boundary, of solution near the center of rotation and tracks the movement of this layer to the outside of the cell as a function of time. Such a method is termed a sedimentary velocity experiment. A