--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Modes of concentration Which of the

    Which of the given modes of expressing concentration is fully independent of temperature: (1) Molarity (2) Molality (3) Formality (4) Normality Choose the right answer from above.

  • Q : Solution and colligative properties

    what is molarity of a solution of hcl which contains 49% by weight of solute and whose specific gravity is 1.41

  • Q : Molal elevation constant of water The

    The boiling point of 0.1 molal aqueous solution of urea is 100.18oC  at 1 atm. The molal elevation constant of water is: (a) 1.8    (b) 0.18   (c) 18    (d) 18.6Answer: (a) Kb

  • Q : HCl is polar or non-polar Can you

    Can you please illustrate that HCl is polar or non-polar? Briefly illustrate it.

  • Q : Problem on normality Help me to solve

    Help me to solve this problem. 0.5 M of H2AO4 is diluted from 1 lire to 10 litre, normality of resulting solution is : (a)1 N (b) 0.1 N (c)10 N (d)11 N

  • Q : Molar mass lculwhat is the equation for

    lculwhat is the equation for caating molar mass of non volatile solute

  • Q : Molarity in Nacl The molarity of 0.006

    The molarity of 0.006 mole of NaCl in 100 solutions will be: (i) 0.6 (ii) 0.06 (iii) 0.006 (iv) 0.066 (v) None of theseChoose the right answer from above.Answer: The right answer is (ii) M = n/ v(

  • Q : Production of alcoholic drinks give all

    give all physical aspects in the production of alcohol

  • Q : Eutectic Formation In some two

    In some two component, solid liquid systems, a eutectic mixture forms.Consider, now a two component system at some fixed pressure, where the temperature range treated is such as to include formation of one or more solid phases. A simple behavior is shown b

  • Q : Latent heat of vaporization Normal

    Normal butane (C4H10) is stored as a compressed liquid at 90°C and 1400 kPa. In order to use the butane in a low-pressure gas-phase process, it is throttled to 150 kPa and passed through a vaporizer. The butane emerges from the vaporizer as a