--%>
Assignment Help - homework help

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Solutions The relative lowering of

    The relative lowering of vapour pressure of 0.2 molal solution in which solvent is benzene

    		•
  • Q : Avogadro's hypothesis Law Principle

    Avogadro's hypothesis Law Principle- Berzelius, a chemist tried

    		•
  • Q : Question relatede to calculate molarity

    Select the right answer of the question. What is molarity of a solution of HCl that contains 49% by weight of solute and whose specific gravity is 1.41 : (a) 15.25 (b) 16.75 (c) 18.92 (d) 20.08

    		•
  • Q : Neutralization of benzoic acid Choose

    Choose the right answer from following. How many grams of NaOH will be required to neutralize 12.2 grams of benzoic acid : (a) 40gms (b) 4gms (c)16gms (d)12.2gms

    		•
  • Q : Advantages of doing your own chemistry

    What are the advantages of doing your own chemistry assignments? State your comment?

    		•
  • Q : Molecular basis of third law. The

    The molecular, or statistical, basis of the third law can be seen by investigating S = k in W.The molecular deductions of the preceding sections have led to the same conclusions as that stated in the third law of thermodynamics, namely, that a value can be

    		•
  • Q : Problem on decinormal strength Can

    Can someone please help me in getting through this problem. How many grams of dibasic acid (having mol. wt. 200) must be present in 100ml  of its aqueous solution to provide decinormal strength: (i) 1g  (ii)2g  (iii) 10g  (iv) 20g<

    		•
  • Q : Problem on solutions The 2N aqueous

    The 2N aqueous solution of H2S04 contains: (a) 49 gm of H2S04 per litre of solution (b) 4.9 gm of H2S04 per litre of solution (c) 98 gm of H2S04

    		•
  • Q : Solution and colligative properties

    what is molarity of a solution of hcl which contains 49% by weight of solute and whose specific gravity is 1.41

    		•
  • Q : Can protein act as the buffer Can

    Can protein act as the buffer? Briefly comment on that statement.

    		•