--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problems related to entropy change A)

    A) Two compartments each of 1 m3 capacity are joined by a valve and insulated from the surroundings and from one another. One compartment has saturated steam at 683.6 kPa and the other contains steam at the same temperature but at a pressure of 101.3 kPa. T

  • Q : Finding Molarity of final mixture Can

    Can someone help me in finding out the right answer. 25ml of 3.0 MHNO3 are mixed with 75ml of 4.0 MHNO3. If the volumes are adding up the molarnity of the final mixture would be: (a) 3.25M (b) 4.0M (c) 3.75M (d) 3.50M

  • Q : Inorganic Chemistry Inorganic

    Inorganic Chemistry:In the year 1869, Russian Chemist Dmitry Mendeleyev forms the periodic table of the element. Since Newlands did before him in the year 1863, Mendeleyev categorizes the el

  • Q : Excel assignment I want it before 8 am

    I want it before 8 am tomorow please. I am just wondering how much is going to be ?

  • Q : Precipitation problem On passing H 2 S 

    On passing H2S  gas through a solution of Cu+ and Zn+2 ions, CuS is precipitated first because: (i) Solubility product of CuS is equal to the ionic product of ZnS (ii) Solubility product of CuS is equal to the solubility product o

  • Q : Explain equilibrium and molecular

    The equilibrium constant can be treated as a particular type of molecular distribution. Consider the simplest gas-phase reaction, one in which molecules of A are converted to molecules of B. the reaction, described by the equation

    Q : Calculating amount of Sodium hydroxide

    Choose the right answer from following. The amount of NaOH in gms in 250cm3 of a0.100M NaOH solution would be : (a) 4 gm (b) 2 gm (c) 1 gm (d) 2.5 gm

  • Q : Calculation of concentration of the

    Choose the right answer from following. 200ml of a solution contains 5.85 dissolved sodium chloride. The concentration of the solution will be(Na= 23: cl = 35.5 ) (a) 1 molar (b) 2 molar (c) 0.5 molar (d) 0.25 molar

  • Q : Group IV Cations Chromium(III)

    Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer.

  • Q : Explain oxygen and its preparation.

    Karl Scheele, the Swedish chemist, was