--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : What is Elevation in boiling point? The

    The boiling of a liquid may be defused by the temperature at which its vapour pressure which is equal to atmospheric pressure. The effect of addition in a non-volatile solute on the boiling point shown and its solution containing non-volatile solute with tempe

  • Q : Latent heat of vaporization Normal

    Normal butane (C4H10) is stored as a compressed liquid at 90°C and 1400 kPa. In order to use the butane in a low-pressure gas-phase process, it is throttled to 150 kPa and passed through a vaporizer. The butane emerges from the vaporizer as a

  • Q : What do you mean by the term dipole

    What do you mean by the term dipole moment? Briefly describe it.

  • Q : Relative lowering in vapour pressure of

    Give me answer of this question. "Relative lowering in vapour pressure of solution containing non-volatile solute is directly proportional to mole fraction of solute". Above statement is: (a) Henry law (b) Dulong and Petit law (c) Raoult's law (d) Le-Chatelier's pri

  • Q : Solubility are halides are halogens

    are halides are halogens more soluble? why?

  • Q : Strength of dilute acid of Sulfuric acid

    Select the right answer of the question.10ml of conc.H2SO4 (18 molar) is diluted to 1 litre. The approximate strength of dilute acid could be: (a)0.18 N (b)0.09 N (c) 0.36 N (d)1800 N

  • Q : Some basic concepts of chemistry an

    an atom of an element is 10.1 times heavier than the mass of a carbon atom.What is its mass in amu?

  • Q : Statement of Henry law Determine the

    Determine the correct regarding Henry’s law: (1) The gas is in contact with the liquid must behave as an ideal gas (2) There must not be any chemical interaction among the gas and liquid (3) The pressure applied must be high (4) All of these.

  • Q : What are Ethers and its types? Ethers

    Ethers are the compounds with general formula or CnH2n+

  • Q : Explain the catalyst definition and

    Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.