--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

  • Q : Molar concentration of Iron chloride

    Provide solution of this question. A certain aqueous solution of FeCl3 (formula mass =162) has a density of 1.1g/ml and contains 20.0% Fecl. Molar concentration of this solution is: (a) .028 (b) 0.163 (c) 1.27 (d) 1.47

  • Q : Strength of the Hydrochloric acid

    Provide solution of this question. 1.0 gm of pure calcium carbonate was found to need 50 ml of dilute HCL for complete reaction. The strength of the HCL solution is specified by : (a) 4 N (b) 2 N (c) 0.4 N (d) 0.2 N

  • Q : Dipole moment direction for the methanol

    Briefly describe the dipole moment direction for the methanol?

  • Q : Forms a molecule to an organic molecule

    Briefly state what forms a molecule to an organic molecule?

  • Q : Molar and Volumetric flow rate problem

    Cyclohexane (C6H12) is produced by mixing Benzene and hydrogen. A process including a reactor, separator, and recycle stream is used to produce Cyclohexane. The fresh feed contains 260L/min C6H6 with 950 L/min of H2

  • Q : Mole fraction in vapours Choose the

    Choose the right answer from following. If two substances A and B have P0A P0B= 1:2 and have mole fraction in solution 1 : 2 then mole fraction of A in vapours: (a) 0.33 (b) 0.25 (c) 0.52 (d) 0.2

  • Q : Molarity 20mol of hcl solution requires

    20mol of hcl solution requires 19.85ml of 0.01 M NAOH solution for complete neutralisation. the molarity of hcl solution

  • Q : Question related to colligative

    The colligative properties of a solution depend on: (a) Nature of solute particles present in it (b) Nature of solvent used (c) Number of solute particles present in it (d) Number of moles of solvent only

  • Q : Problem on making solution Select the

    Select the right answer of the question. The weight of H2C2O42H2O required to prepare 500ml of 0.2N solution is : (a) 126g (b) 12.6g (c) 63g (d) 6.3g