--%>

Problem on reversible and irreversible process

The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.  

a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
 
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.

   Related Questions in Chemistry

  • Q : Dipole moment Elaborate a dipole moment

    Elaborate a dipole moment?

  • Q : What are homogenous catalyst? Give few

    When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are:    SO2

  • Q : Surface Tension Vapour Pressure The

    The vapor pressure of small liquid drops depends on the drop size. Although the surface properties of a liquid are different from those of the bulk liquid, the special surface properties can be ignored except in a few situations. One is the case in which a liquid is dispersed into fine dr

  • Q : Problem on distribution law The

    The distribution law is exerted for the distribution of basic acid among: (i) Water and ethyl alcohol (ii) Water and amyl alcohol (iii) Water and sulphuric acid (iv) Water and liquor ammonia What is the right answer.

  • Q : What is ortho effect? Orthosubstituted

    Orthosubstituted anilines are generally weaker bases than aniline irrespective of the electron releasing or electron withdrawing nature of the substituent. This is known as ortho effect and may probably be due to combined electronic and steric factors.The overall basic strength of ort

  • Q : Reducible Representations The number of

    The number of times each irreducible representation occurs in a reducible representation can be calculated.Consider the C2v point group as described or Appendix C. you can see that (1) sum of

  • Q : Explain the preparation of phenols. The

    The methods used for the preparation of phenols are given below:    From aryl sulphonic acids

  • Q : Problem on making solution Select the

    Select the right answer of the question. The weight of H2C2O42H2O required to prepare 500ml of 0.2N solution is : (a) 126g (b) 12.6g (c) 63g (d) 6.3g

  • Q : How to establish nomenclature for

    In the common chemistry terminologies, aliphatic halogen derivatives are named as alkyl halides. The words, n-, sec-, tert-, iso-, neo-, and amyl are

  • Q : Problems related to entropy change A)

    A) Two compartments each of 1 m3 capacity are joined by a valve and insulated from the surroundings and from one another. One compartment has saturated steam at 683.6 kPa and the other contains steam at the same temperature but at a pressure of 101.3 kPa. T