--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : How to calculate solutions molar

    The contribution of an electrolyte, or an ion electrolyte, is reported as the molar of a conductance. The definition of the molar conductance is based on the following conductivity cell in which the electrodes are 1 m apart and of sufficient area that th

    		•
  • Q : Calculation of concentration of the

    Choose the right answer from following. 200ml of a solution contains 5.85 dissolved sodium chloride. The concentration of the solution will be(Na= 23: cl = 35.5 ) (a) 1 molar (b) 2 molar (c) 0.5 molar (d) 0.25 molar

    		•
  • Q : Osmotic Pressure The O.P. (Osmotic

    The O.P. (Osmotic Pressure) of equimolar solution of Urea, BaCl2 and AlCl3, will be in the order:(a) AlCl3 > BaCl2 > Urea  (b) BaCl2 > AlCl3 > Urea  (c) Urea > BaCl2<

    		•
  • Q : Problem on mol fraction of naphthalene

    At 20°C the solubility of solid naphthalene in hexane is 0.09 mol/mol of solution. Use this information and the data below to estimate the following for this system: a) The mol fraction of naphthalene in the vapour phase in equ

    		•
  • Q : Real vapour pressure Choose the right

    Choose the right answer from following. The pressure under which liquid and vapour can coexist at equilibrium is called the : (a) Limiting vapour pressure (b) Real vapour pressure (c) Normal vapour pressure (d) Saturated vapour pressure

    		•
  • Q : Means of molal solution Choose the

    Choose the right answer from following. A molal solution is one that contains one mole of a solute in: (a) 1000 gm of the solvent (b) One litre of the solvent (c) One litre of the solution (d) 22.4 litres of the solution

    		•
  • Q : P- block why pentahalids are more

    why pentahalids are more covalent than tetrahalids

    		•
  • Q : Nuclear Magnetic Resonance The nuclear

    The nuclear states produced by a magnetic field are studied in nuclear magnetic resonance spectroscopy.The frequency of the radiation that corresponds to the nuclear magnetic energy level spacings and the weakness of the radiation absorption that must be e

    		•
  • Q : Explain structure basicity of amines.

    Basic character of amines is related to their structural arrangement. Basic strength of amines depends on the relative ease of formation of the corresponding cation by accepting a proton from the acid. Greater the stability of cation is, more is basic strength of amine.Alkyl a

    		•
  • Q : Vapour pressure of a liquid Help me to

    Help me to go through this problem. The vapour pressure of a liquid depends on: (a) Temperature but not on volume (b) Volume but not on temperature (c) Temperature and volume (d) Neither on temperature nor on volume

    		•