--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : P block why BiF3 is ionic whereas other

    why BiF3 is ionic whereas other trihalides are covalent in nature?

    		•
  • Q : Acid value definition The acid value

    The acid value definition is the number milligrams of KOH needed to neutralize the acid present in one gram oil and fats however why not employ NaOH for the neutralization?

    		•
  • Q : Problem based on lowering in vapour

    Help me to solve this problem. An aqueous solution of glucose was prepared by dissolving 18 g of glucose in 90 g of water. The relative lowering in vapour pressure is: (a) 0.02 (b)1 (c) 20 (d)180

    		•
  • Q : Problem on moles of solution The number

    The number of moles of a solute in its solution is 20 and total no. of moles are 80. The mole fraction of solute wil be: (a) 2.5 (b) 0.25 (c) 1 (d) 0.75

    		•
  • Q : Explain physical properties of

    . Boiling pointsThe boiling points of monohalogen derivatives of benzene, which are all liquids, follow the orderIodo > Bromo > ChloroThe boiling points of isomeric dihalobe

    		•
  • Q : What are biodegradable polymers?

      These are polymers that can be broken into small segments by enzyme-catalysed reactions. The required enzymes are produced by microorganism. It is a known fact that the carbon-carbon bonds of chain growth polymers are inert to enzyme-catalysed reactions, and hence they are non biod

    		•
  • Q : Facts on evaporation Illustrate the 3

    Illustrate the 3 facts on evaporation?

    		•
  • Q : Problem based on molarity Choose the

    Choose the right answer from following. The molarity of a solution of Na2CO3 having 10.6g/500ml of solution is : (a) 0.2M (b)2M (c)20M (d) 0.02M

    		•
  • Q : Vapour pressure of volatile substance

    Provide solution of this question. According to Raoult's law the relative lowering of vapour pressure of a solution of volatile substance is equal to: (a) Mole fraction of the solvent (b) Mole fraction of the solute (c) Weight percentage of a solute (d) Weight perc

    		•
  • Q : Haloalkene with the help of polarity of

    with the help of polarity of c-x bond show that aryl halides are less reactive than alkyl halides

    		•