--%>

Linde liquefaction process

Liquefied natural gas (LNG) is produced using a Linde liquefaction process from pure methane gas at 3 bar and 280 K (conditions at point 1 in figure below). A three-stage compressor with interceding is used to compress the methane to 100 bar (point 2). The first stage compresses the gas from 1 bar to 5 bar, the second stage from 5 bar to 25 bar, and the tiiird stage from 25 bar to 100 bar. Between stages the gas Is isobarically cooled to 280 K. Each stage of the compressor can be assumed to operate reversibly and adiabaticaliy. The methane leaving the cooler is at 100 bar and 210 K (point 3). The flash dram is adiabatic and operates at! bar. The recycled methane leaving the heat exchanger (point 5') is at I bar and 200 K.

a) Calculate the fractions of vapour and liquid leaving the flash drum {Hint: write balance equations around the subsystem consisting of the heat exchanger, throttle valve and flash drum).

b) Calculate the temperature at the inlet of the compressor (point I).

c) Calculate the amount of work required for each kilogram of methane that passes through the compressor.

d) Calculate the amount of compressor work required for each kilogram of LNG produced.

e) Calculate

i) the heat removal after the first and second stages of the compressor,
ii) the heat removed in the cooler, and
iii) the heat exchanged in the heat exchanger.

Express all values in kJ/kg of methane that passes through the compressor.

Data: The thermodynamic properties of methane are given in the attached diagram.

71_diagram.jpg

   Related Questions in Chemistry

  • Q : Question based on relative lowering of

    Give me answer of this question. When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is equal to: (a) Mole fraction of solute (b) Mole fraction of solvent (c) Concentration of the solute in grams per litre

  • Q : What is schrodinger wave equation? The

    The Schrodinger wave equation generalizes the fitting-in-of-waves procedure.The waves that "fit" into the region to which the particle is contained can be recognized "by inspection" only for a few simple systems. For other problem a mathematical procedure

  • Q : What are electromotive force in

    The main objective of this particular aspect of Physical Chemistry is to examine the relation between free energies and the mechanical energy of electromotive force of electrochemical cells. The ionic components of aqueous solutions can be treated on the basis of the

  • Q : Problem on molecular weight of solid

    The vapor pressure of pure benzene at a certain temperature is 200 mm Hg. At the same temperature the vapor pressure of a solution containing 2g of non-volatile non-electrolyte solid in 78g of benzene is 195 mm Hg. What is the molecular weight of solid:

  • Q : What are diazonium salts? The diazonium

    The diazonium salts are represented by the general formula ArN2 +X where X- ion may be anion such as (Cl) ¨, B ¨r, HSO

  • Q : Avogadros hypothesis how avogadros

    how avogadros hypothesis used to deduce the atomicity of elementry gases ?

  • Q : Problem on Adiabatic expansion

    Calculate the change in entropy for the system for each of the following cases. Explain the sign that you obtain by a physical argument a) A gas undergoes a reversible, adiabatic expansion from an initial state at 500 K, 1 MPa, and

  • Q : Problem on relative volatility In

    In vapor-liquid equilibrium the relative volatility αij is defined to be the ratio of the separation or K factor for species i to that for species j, that is,  αij = Ki/Kj

  • Q : Degree of dissociation The degree of

    The degree of dissociation of Ca(No3)2 in a dilute aqueous solution containing 14g of the salt per 200g of water 100oc is 70 percent. If the vapor pressure of water at 100oc is 760 cm. Calculate the vapor pr

  • Q : Define thermal energy The thermal part

    The thermal part of the internal energy and the enthalpy of an ideal gas can be given a molecular level explanation. All the earlier development of internal energy and enthalpy has been "thermodynamic". We have made no use o