amines
why o-toluidine is a weaker base than aniline?
In some two component, solid liquid systems, a eutectic mixture forms.Consider, now a two component system at some fixed pressure, where the temperature range treated is such as to include formation of one or more solid phases. A simple behavior is shown b
Choose the right answer from following. At 300 K, when a solute is added to a solvent its vapour pressure over the mercury reduces from 50 mm to 45 mm. The value of mole fraction of solute will be: (a)0.005 (b)0.010 (c)0.100 (d)0.900
The bonding in ionic molecules can be described with a coulombic attractive term.For some diatomic molecules we take quite a different approach from that used in preceding sections to describe the bonding. Ionic bonds are interpreted in terms of the coulom
Choose the right answer from following. An X molal solution of a compound in benzene has mole fraction of solute equal to 0.2. The value of X is: (a)14 (b) 3.2 (c) 4 (d) 2
Calculate the change in entropy for the system for each of the following cases. Explain the sign that you obtain by a physical argument a) A gas undergoes a reversible, adiabatic expansion from an initial state at 500 K, 1 MPa, and
Write a short note to describe how to test a gas to see if it was hydrogen or not?
The constant of vander Waal's equation can be related to the coefficients of the virial equation. Vander Waal's equation provides a good overall description of the real gas PVT behaviour. Now let us
Choose the right answer from following. What is the molarity of H2SO4 solution, that has a density 1.84 gm/cc at 35c and contains solute 98% by weight: (a) 4.18 M (b) 8.14 M (c)18.4 M (d)18 M
The important methods for the preparation of alcohol on large-scale are given below:  
The process of adsorption can occurs in solutions also. This implies that the solid surfaces can also adsorb solutes from solutions. Some clarifying examples are listed below: (i) When an aqueous solution of ethano
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