What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Can someone please help me in getting through this problem. Concentrated H2SO4 has a density of 1.98 gm/ml and is 98% H2SO4 by weight. The normality is: (a) 2 N (b) 19.8 N (c) 39.6 N (d) 98
Provide solution of this question.10N/and 1/10N solution is called: (a) Decinormal and decanormal solution (b) Normal and decinormal solution (c) Normal and decanormal solution (d) Decanormal and decinormal solution
Whether HCl is a base or an acid? Briefly state your comments?
Briefly describe the function of the monosaccharide?
The edge length of the unit cell of Nacl crystal lattice is 552 pm. If ionic radius of sodium ion is 95. What is the ionic radius of chloride ion:(a) 190 pm (b) 368 pm (c) 181 pm (d) 276 pm <
What is the normal amount of glucose in 100ml of blood (8–12 hrs after meal) is: (i) 8mg (ii) 80mg (iii) 200mg (iv) 800mg Choose the right answer from above.
Superphosphate has the formulate: CaH4 (PO4)2 H2O calculate the percentage of Phosphorus in this chemical. Show your calculations
Choose the right answer from following. The magnitude of colligative properties in all colloidal dispersions is : (a) Lowerthan solution (b)Higher than solution(c) Both (d) None
Haloalkanes are extremely reactive category of aliphatic compounds. Their reactivity is due to the presence of polar carbon-halogen bond in their mole
Mole fraction of any solution is equavalent to: (a) No. of moles of solute/ volume of solution in litter (b) no. of gram equivalent of solute/volume of solution in litters (c) no. of moles of solute/ Mass of solvent in kg (d) no. of moles of any
18,76,764
1922779 Asked
3,689
Active Tutors
1427139
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!