What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.
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Choose the right answer from following. If two substances A and B have P0A P0B= 1:2 and have mole fraction in solution 1 : 2 then mole fraction of A in vapours: (a) 0.33 (b) 0.25 (c) 0.52 (d) 0.2
Give me answer of this question. A solution contains 25%H2O 25%C2H5OH , and 50% CH3 COOH by mass. The mole fraction of H2O would be: (a) 0.25 (b) 2.5 (c) 0.503 (d) 5.03.
what is the relationship between vitamins and enzyme cofactors
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