What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Give me answer of this question. When a substance is dissolved in a solvent the vapour pressure of the solvent is decreased. This results in: (a) An increase in the b.p. of the solution (b) A decrease in the b.p. of the solvent (c) The solution having a higher fr
Nucleophilic substitution reactions in halides containing - X bond may take place through either of the two different mechanisms,S<
Help me to go through this problem. The vapour pressure of a liquid depends on: (a) Temperature but not on volume (b) Volume but not on temperature (c) Temperature and volume (d) Neither on temperature nor on volume
give atleast two application of following colligative properties
Choose the right answer from following. If P and P are the vapour pressure of a solvent and its solution respectively N1 and N2 and are the mole fractions of the solvent and solute respectively, then correct relation is: (a) P= PoN1 (b) P= Po N2 (c)P0= N2 (d)
Provide solution of this question. In an experiment, 1 g of a non-volatile solute was dissolved in 100 g of acetone (mol. mass = 58) at 298K. The vapour pressure of the solution was found to be 192.5 mm Hg. The molecular weight of the solute is (vapour pressure of ace
Give me answer of this question. When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is equal to: (a) Mole fraction of solute (b) Mole fraction of solvent (c) Concentration of the solute in grams per litre (d) Concentratio
Provide solution of this question.10N/and 1/10N solution is called: (a) Decinormal and decanormal solution (b) Normal and decinormal solution (c) Normal and decanormal solution (d) Decanormal and decinormal solution
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4
Average covalent radii can be assigned on the basis of molecular structures. The accumulation of structural data by spectroscopic studies and both electron and x-ray diffraction studies allows one to investigate the possibili
18,76,764
1925441 Asked
3,689
Active Tutors
1449882
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!