What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Liquid solutions are obtained when the solvent is liquid. The solute can be a gas, liquid or a solid. In this section we will discuss the liquid solutions containing solid or liquid solutes. In such solutions the solute may or may not be volatile. We shall limit our d
Which ion has the lowest radius from the following ions(a) Na+ (b) Mg2+ (c) Al3+ (d) Si4+ Answer: (d) All are the iso-electronic species but Si
Provide solution of this question. The weight of sodium carbonate required to prepare 500 ml of a seminormal solution is: (a) 13.25 g (b) 26.5 g (c) 53 g (d) 6.125 g
The ionic radii of Rb+ and I- respectively are 1.46 Å and 2.16Å. The very most probable type of structure exhibited by it is: (a) CsCl type (b) ZnS type (c) Nacl type (d) CaF2 type Q : Ionization Potential Second ionization Second ionization potential of Li, Be and B is in the order (a)Li>Be>B (b)Li>B>Be (c)Be>Li>B (d)B>Be>Li
Second ionization potential of Li, Be and B is in the order (a)Li>Be>B (b)Li>B>Be (c)Be>Li>B (d)B>Be>Li
lculwhat is the equation for caating molar mass of non volatile solute
Describe briefly the functions of centrioles?
The average translational kinetic energies and speeds of the molecules of a gas can be calculated.The result that the kinetic energy of 1 mol of the molecules of a gas is equal to 3/2 RT can be used to obtain numerical values for the
I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267
the death cap mushroom based on your knowledge of the biochemistry of dna and rna
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