--%>
Assignment Help - homework help

Problem on decomposition reaction

Nitrogen tetroxide (melting point: -11.2°C, normal boiling point 21.15°C) decomposes into nitrogen dioxide according to the following reaction:

N2O4(g) ↔ 2 NO2(g)

The decomposition reaction is fast and the color of the gas goes from clear to brown as the extent of dissociation increases. Using only the experimental data presented below, answer the following questions.

a) Is the decomposition reaction endothermic or exothermic? Why?

b) What is the extent of dissociation at 61.8°C and 1 bar if the initial state consists of pure N2O4?

c) Repeat part (b) for the case where the total pressure is 0.5 bar.

d) Repeat part (b) for the case where the initial state consists of 50 mol% inerts and 50 mol% N2O4.

e) Determine Δhorxn at 47.7°C.

f) Determine Δgorxn, at 47.7°C

g) Determine Δsorxn, at 47.7°C

Data:

1706_endo or exo.jpg

   Related Questions in Chemistry

  • Q : Mass percent Help me to go through this

    Help me to go through this problem. 10 grams of a solute is dissolved in 90 grams of a solvent. Its mass percent in solution is : (a) 0.01 (b) 11.1 (c)10 (d) 9

    		•
  • Q : Mole 2.0gram of dolomite is heated to a

    2.0gram of dolomite is heated to a constant weight of 1.0g. Calculate the total volume of CO2 produced at STP by this reation

    		•
  • Q : Define thermal energy The thermal part

    The thermal part of the internal energy and the enthalpy of an ideal gas can be given a molecular level explanation. All the earlier development of internal energy and enthalpy has been "thermodynamic". We have made no use o

    		•
  • Q : Linde liquefaction process Liquefied

    Liquefied natural gas (LNG) is produced using a Linde liquefaction process from pure methane gas at 3 bar and 280 K (conditions at point 1 in figure below). A three-stage compressor with interceding is used to compress the methane to 100 bar (point 2). The first stage

    		•
  • Q : What are methods of phenol preparation

    Phenol was initially obtained by fractional distillation of coal

    		•
  • Q : Direction of dipole moment expected

    Illustrate the direction of the dipole moment expected for hydrogen bromide?

    		•
  • Q : Hydrocarbons list and identify

    list and identify differences between the major classes of hydrocarbons

    		•
  • Q : Pressure and power for adiabatic

    a) Air flowing at 1 m3/s enters an adiabatic compressor at 20°C and 1 bar. It exits at 200°C. The isentropic efficiency of the compressor is 80%. Calculate the exit pressure and the power required. b) Steam enter

    		•
  • Q : Carnot cycle show how a mathematical

    show how a mathematical definition of entropy can be obtauined from a consideration of carnot cycle?

    		•
  • Q : Amines arrange in order of

    arrange in order of basicity,pyridine,pipyridineand pyorine

    		•