--%>
Assignment Help - homework help

What are the chemical properties of haloalkanes?

Haloalkanes are extremely reactive category of aliphatic compounds. Their reactivity is due to the presence of polar carbon-halogen bond in their molecules.


The chemical reactions of haloalkanes can be divided into four ways:
    
Nucleophilic substitution reactions

In haloalkanes, the halogen atoms are attached to the carbon atom. The bond between carbon and halogen is polar in character because the halogen atom is more electronegative than carbon.

Due to the presence of partial positive charge on the carbon atom, the nucleophilies can attack on electron deficient carbon thereby resulting the displacement of weaker nucleophile is generally stronger than it.

The order of reactivity of various alkyl halides towards nucleophilic substitution in the order:

Order of reactivity: RI > RBr > RCI > RF

This order of reactivity can be explained on the basis of strength of C-X bond. The C-X bond is the weakest in R-I and the strongest in R-F as is clear from the bond energy data for methyl halides. In fact, the C-F bond is so strong that organic fluorides do not undergo nucleophilic substitution under ordinary conditions.

Bond

C-I

C-Br

C-Cl

C-F

Bond Enthalpies (kJ/mole)

234

293

351

452

Bond length (pm)

214

193

178

139

Dipole moment (Debye)

1.636

1.830

1.860

1.847


Examples of nucleophilic substitution reactions of haloalkanes
    
Replacement of hydroxyl group (Formation of alcohols).

Haloalkanes on treatment with aqueous solution of KOH or moist silver oxide (Ag2O/H2O) give alcohols.
                        
2388_haloalkanes.png 
    
Replacement Alkoxy group (Formation of ethers). (Williamson Synthesis):

Haloalkanes on treatment with alcoholic sodium or potassium alkoxide form ethers. This reaction is called as Williamson Synthesis.
        
1935_haloalkanes1.png 

Ethers can also be prepared by heating alkyl halides with dry silver oxide, Ag2O
                
1005_haloalkanes3.png  
    
Replacement by Cyano Group (Formation of cyanides or nitrites)

Haloalkanes on treatment with alcoholic KCN solution give alkanenitriles or alkyl cyanides as the major product with a small amount of alkyl isocyanide.

2173_haloalkanes2.png 

The reaction of alkyl halides with KCN gives us an important method for increasing the length of carbon chain by one carbon atom i.e. rising of series.

   Related Questions in Chemistry

  • Q : Which is polar HCl or HF Which one is

    Which one is polar HCl or HF?

    		•
  • Q : Number of mlecules in methane Can

    Can someone please help me in getting through this problem. The total number of molecules in 16 gm of methane will be: (i) 3.1 x 1023 (ii) 6.02 x 1023 (iii) 16/6.02 x 1023 (iv) 16/3.0 x 1023

    		•
  • Q : Explain physical properties of

    . Boiling pointsThe boiling points of monohalogen derivatives of benzene, which are all liquids, follow the orderIodo > Bromo > ChloroThe boiling points of isomeric dihalobe

    		•
  • Q : Value of molar solution Select the

    Select the right answer of the question. Molar solution contains: (a)1000g of solute (b)1000g of solvent (c)1 litre of solvent (d)1 litre of solution

    		•
  • Q : Relationship between free energy and

    The free energy of a gas depends on the pressure that confines the gas. The standard free energies of formation, like those allow predictions to be made of the possibility of a reaction at 25°C for each reagent at 

    		•
  • Q : Thermodynamics 1 Lab Report I already

    I already did Materials and Methods section. I uploaded it with the instructions. Also, make sure to see Concept Questions and Thinking Ahead in the instructions that I uploaded. deadline is tomorow at 8 am here is the link to download all instructions because I couldn't attach all of t

    		•
  • Q : Problem on equilibrium composition The

    The catalytic dehydrogenation of 1-butene to 1,3-butadiene, C4H8(g) = C4H6(g)+H2(g) is carried out at 900 K and 1 atm.

    Q : Determining of normality of sodium

    Can someone please help me in getting through this problem. The normality of a solution of sodium hydroxide 100 ml of which includes 4 grams of NaOH is: (a) 0.1 (b) 40 (c) 1.0 (d) 0.4

    		•
  • Q : Describe characteristics of halides and

    Halides characteristics

    		•
  • Q : Relative lowering of vapour pressure

    explain the process of relative lowering of vapour pressure

    		•