--%>

How reactive is Trimethylindium towards oxygen and water

Illustrate the reason, how reactive is Trimethylindium towards oxygen and water?

E

Expert

Verified

The Trimethylindium is extremely reactive to oxygen and water. With a low concentrations of oxygen (ppb to ppm to a few %), Trimethylindium instantly procedures dimethylindium methoxide (Me2InOMe) as the first reaction product by the insertion of O between In and C. With increased concentrations of oxygen (several %, atmospheric air or pure oxygen), it burns or explodes. Like insertion reactions are expected with another elements of Group 16 (as S, Se and Te) with highly vigorous outburst at higher concentrations of S, Te and Se.
Trimethylindium reacts energetically and freely with the water to form Me2InOH and Methane (CH4) gas if concentration of H2O is much small (up to 1000's ppm). With high concentrations of water (% level), trimethylindium can burn and repeatedly explode leaving behind In (OH)3, In2O3 as final products. Extremely violent reactions of trimethylindium are known with oxidizers. Like H2O2, KMnO4, HNO3, Bleach) and halogenated compounds (CCl4, CBrCl3, CBr2Cl2, C2Cl6, CHCl3 and halocarbon oils).

   Related Questions in Chemistry

  • Q : Relative lowering of vapour pressure

    Which of the following solutions will have a lower vapour pressure and why? a) A 5% aqueous solution of cane sugar. b) A 5% aqueous solution of urea.

  • Q : Electrochemistry ( electrolysis of

    1. Define Faraday's first law of electrolysis 2. define Faraday's second law of electrolysis

  • Q : Sugar solution The solution of sugar in

    The solution of sugar in water comprises: (i) Free atoms (ii) Free ions (iii) Free molecules (iv) Free atom and molecules. Choose the right answer from the above.

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

  • Q : Problem on molality Select the right

    Select the right answer of the question. Calculate the molality of 1 litre solution of 93% H2SO4 (weight/volume). The density of the solution is 1.84 g /ml : (a) 10.43 (b) 20.36 (c) 12.05 (d) 14.05

  • Q : PH of an Alkyl Halide Briefly state the

    Briefly state the pH of an Alkyl Halide?

  • Q : Microwave Adsorption The absorption of

    The absorption of microwave radiation increases the rotational energy of molecules and gives information about the moment of inertia of the molecules.Now we can begin the study of the spectroscopy that explores the different ways in which the energy of the

  • Q : Distribution law Help me to go through

    Help me to go through this problem. The distribution law is applied for the distribution of basic acid between : (a) Water and ethyl alcohol (b) Water and amyl alcohol (c) Water and sulphuric acid (d) Water and liquor ammonia

  • Q : Molal elevation constant of water The

    The boiling point of 0.1 molal aqueous solution of urea is 100.18oC  at 1 atm. The molal elevation constant of water is: (a) 1.8    (b) 0.18   (c) 18    (d) 18.6Answer: (a) Kb

  • Q : Problem on making solution Select the

    Select the right answer of the question. The weight of H2C2O42H2O required to prepare 500ml of 0.2N solution is : (a) 126g (b) 12.6g (c) 63g (d) 6.3g