--%>

How reactive is Trimethylindium towards oxygen and water

Illustrate the reason, how reactive is Trimethylindium towards oxygen and water?

E

Expert

Verified

The Trimethylindium is extremely reactive to oxygen and water. With a low concentrations of oxygen (ppb to ppm to a few %), Trimethylindium instantly procedures dimethylindium methoxide (Me2InOMe) as the first reaction product by the insertion of O between In and C. With increased concentrations of oxygen (several %, atmospheric air or pure oxygen), it burns or explodes. Like insertion reactions are expected with another elements of Group 16 (as S, Se and Te) with highly vigorous outburst at higher concentrations of S, Te and Se.
Trimethylindium reacts energetically and freely with the water to form Me2InOH and Methane (CH4) gas if concentration of H2O is much small (up to 1000's ppm). With high concentrations of water (% level), trimethylindium can burn and repeatedly explode leaving behind In (OH)3, In2O3 as final products. Extremely violent reactions of trimethylindium are known with oxidizers. Like H2O2, KMnO4, HNO3, Bleach) and halogenated compounds (CCl4, CBrCl3, CBr2Cl2, C2Cl6, CHCl3 and halocarbon oils).

   Related Questions in Chemistry

  • Q : Group Cations Explain how dissolving

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid, establishes a buffer with a pH of approximately

  • Q : Entropy is entropy on moleculare basis

    is entropy on moleculare basis relates to the tras.,vib.,and rotational motions?

  • Q : Neutralization of sodium hydroxide How

    How much of NaOH is needed to neutralise 1500 cm3 of 0.1N HCl (given = At. wt. of Na =23): (i) 4 g  (ii) 6 g (iii) 40 g  (iv) 60 g

  • Q : Molar concentration of Iron chloride

    Provide solution of this question. A certain aqueous solution of FeCl3 (formula mass =162) has a density of 1.1g/ml and contains 20.0% Fecl. Molar concentration of this solution is: (a) .028 (b) 0.163 (c) 1.27 (d) 1.47

  • Q : Determining mole fraction of water in

    A mixture has 18 g water and 414 g ethanol. What is the mole fraction of water in mixture (suppose ideal behaviour of mixture): (i) 0.1  (ii) 0.4  (iii) 0.7  (iv) 0.9 Choose the right answer from abo

  • Q : Question associated to vapour pressure

    Choose the right answer from following. The vapour pressure lowering caused by the addition of 100 g of sucrose(molecular mass = 342) to 1000 g of water if the vapour pressure of pure water at 25degree C is 23.8 mm Hg: (a)1.25 mm Hg (b) 0.125 mm Hg (c) 1.15 mm H

  • Q : Haloalkane how haloalkane can be

    how haloalkane can be prepared by refluxing alcohol with hydrohalic acids

  • Q : Molecular Structure type The ionic

    The ionic radii of Rb+ and I- respectively are 1.46 Å and 2.16Å. The very most probable type of structure exhibited by it is: (a) CsCl type  (b) ZnS type  (c) Nacl type  (d) CaF2 type

    Q : Equimolar solutions Select the right

    Select the right answer of the question. Equimolar solutions in the same solvent have : (a)Same boiling point but different freezing point (b) Same freezing point but different boiling poin (c)Same boiling and same freezing points (d) Different boiling and differe

  • Q : Question based on lowest vapour pressure

    Give me answer of this question. Among the following substances the lowest vapour pressure is exerted by: (a) Water (b) Mercury (c) Kerosene (d) Rectified spirit