--%>

How reactive is Trimethylindium towards oxygen and water

Illustrate the reason, how reactive is Trimethylindium towards oxygen and water?

E

Expert

Verified

The Trimethylindium is extremely reactive to oxygen and water. With a low concentrations of oxygen (ppb to ppm to a few %), Trimethylindium instantly procedures dimethylindium methoxide (Me2InOMe) as the first reaction product by the insertion of O between In and C. With increased concentrations of oxygen (several %, atmospheric air or pure oxygen), it burns or explodes. Like insertion reactions are expected with another elements of Group 16 (as S, Se and Te) with highly vigorous outburst at higher concentrations of S, Te and Se.
Trimethylindium reacts energetically and freely with the water to form Me2InOH and Methane (CH4) gas if concentration of H2O is much small (up to 1000's ppm). With high concentrations of water (% level), trimethylindium can burn and repeatedly explode leaving behind In (OH)3, In2O3 as final products. Extremely violent reactions of trimethylindium are known with oxidizers. Like H2O2, KMnO4, HNO3, Bleach) and halogenated compounds (CCl4, CBrCl3, CBr2Cl2, C2Cl6, CHCl3 and halocarbon oils).

   Related Questions in Chemistry

  • Q : Define Virial Equation The constant of

    The constant of vander Waal's equation can be related to the coefficients of the virial equation.  Vander Waal's equation provides a good overall description of the real gas PVT behaviour. Now let us

  • Q : Question based on vapour pressure and

    Benzene and toluene form nearly ideal solutions. At 20°C, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The parial vapour pressure of benzene at 20°C for a solution containing 78g of benzene and 46g of toluene in torr is: (a) 50 (b)

  • Q : Calculate PH value for a acetic acid 1.

    1. A solution of 0.100 M acetic acid is prepared. a) What is its pH value? b) If 20% of the initial acetic acid is converted to the acetate form by titration with NaOH, what is the resultant pH?

  • Q : Problem on Neutralization What weight

    What weight of hydrated oxalic acid should be added for complete neutralisation of 100 ml of 0.2N - NaOH solution? (a) 0.45 g  (b)0.90 g  (c) 1.08 g  (d) 1.26 g      Answer

  • Q : Problem based on molality of glucose

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

  • Q : Show your calculations Superphosphate

    Superphosphate has the formulae: CaH4 (PO4)2H2).  Calculate the percentage of phosphorus in this chemical.  Show your calculations  (around ten lines);  also Work out how to make up a nutrient mixtur

  • Q : Effect of addition of mercuric iodide

    Give me answer of this question. When mercuric iodide is added to the aqueous solution of potassium iodide, the:(a) Freezing point is raised (b) Freezing point is lowered (c) Freezing point does not change (d) Boiling point does not change

  • Q : Benefits of soapy detergents over the

    What are the benefits of soapy detergents over the soap less detergents? Briefly state the benefits?

  • Q : Moles of chloride ion Select the right

    Select the right answer of the question. A solution of CaCl2 is 0.5 mol litre , then the moles of chloride ion in 500ml will be : (a) 0.25 (b) 0.50 (c) 0.75 (d)1.00

  • Q : Question associated to vapour pressure

    Choose the right answer from following. The vapour pressure lowering caused by the addition of 100 g of sucrose(molecular mass = 342) to 1000 g of water if the vapour pressure of pure water at 25degree C is 23.8 mm Hg: (a)1.25 mm Hg (b) 0.125 mm Hg (c) 1.15 mm H