--%>
Assignment Help - homework help

How reactive is Trimethylindium towards oxygen and water

Illustrate the reason, how reactive is Trimethylindium towards oxygen and water?

E

Expert

Verified

The Trimethylindium is extremely reactive to oxygen and water. With a low concentrations of oxygen (ppb to ppm to a few %), Trimethylindium instantly procedures dimethylindium methoxide (Me2InOMe) as the first reaction product by the insertion of O between In and C. With increased concentrations of oxygen (several %, atmospheric air or pure oxygen), it burns or explodes. Like insertion reactions are expected with another elements of Group 16 (as S, Se and Te) with highly vigorous outburst at higher concentrations of S, Te and Se.
Trimethylindium reacts energetically and freely with the water to form Me2InOH and Methane (CH4) gas if concentration of H2O is much small (up to 1000's ppm). With high concentrations of water (% level), trimethylindium can burn and repeatedly explode leaving behind In (OH)3, In2O3 as final products. Extremely violent reactions of trimethylindium are known with oxidizers. Like H2O2, KMnO4, HNO3, Bleach) and halogenated compounds (CCl4, CBrCl3, CBr2Cl2, C2Cl6, CHCl3 and halocarbon oils).

   Related Questions in Chemistry

  • Q : Basicity order order of decreasing

    order of decreasing basicity of urea and its substituents

    		•
  • Q : Calculating total number of moles

    Choose the right answer from following. While 90 gm of water is mixed with 300 gm of acetic acid. The total number of moles will be: (a)5 (b)10 (c)15 (d)20

    		•
  • Q : Vapour pressure Vapour pressure of

    Vapour pressure of methanol in water Give me answer of this question. An aqueous solution of methanol in water has vapour pressure: (a) Equal to that of water (b) Equal to that of methanol (c) More than that of water (d) Less than that of water

    		•
  • Q : Problem on reversible and irreversible

    The second law states that  dS ≥ (dQ/T), where dS = dQ/T for a reversible process and dS > dQ/T for an irreversible process.   a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a r

    		•
  • Q : Benzoic acid is weaker than paranitro

    Briefly state that Benzoic acid is weaker than paranitro benzoic acid?

    		•
  • Q : Colligative effect Choose the right

    Choose the right answer from following. Which one of the statements written below concerning properties of solutions, explain a colligative effect: (a) Boiling point of pure water decreases by the addition of ethano (b) Vapour pressure of pure water d

    		•
  • Q : Reducible Representations The number of

    The number of times each irreducible representation occurs in a reducible representation can be calculated.Consider the C2v point group as described or Appendix C. you can see that (1) sum of

    		•
  • Q : Freezing point of equimolal aqueous

    The freezing point of equi-molal aqueous solution will be maximum for:            (a) C6H5NH3+Cl-(aniline hydrochloride)  (b) Ca(NO3

    		•
  • Q : Electrochemistry ( electrolysis of

    1. Define Faraday's first law of electrolysis 2. define Faraday's second law of electrolysis

    		•
  • Q : What do you mean by the term Organic

    What do you mean by the term Organic Chemistry? Briefly define the term?

    		•