Introduction:
We are familiar that hydrocarbons as organic compound comprising of carbon and hydrogen only. We were as well identifying that hydrocarbons can simply be categorized into alkanes, alkenes, alkynes and aromatic (particularly benzene) compounds. The nomenclature of such classes of hydrocarbon was as well illustrated.
The alkanes, having a general formula CnH 2n+2 or RH is the simplest homologous series and comprise of saturated hydrocarbons.
Alkanes, being saturated hydrocarbons are somewhat inert and don't undergo any reaction other than combustion and substitution. They play a significant part in petroleum chemistry. Alkanes are as well termed to as paraffins from the Latin words meaning a little affinity. As alkanes have atoms which are linked by only single bonds (that is, saturation), the few chemical reactions they experience is mainly of substitution type reactions-one atom being replaced by the other.
Natural Sources of Alkanes:
Natural Gas:
This is one of the main sources of alkanes. The natural gas is found in the strata of earth in various parts of the universe, example - Kuwait, Saudi Arabia, Nigeria, USA, Iraq and so on, and it is at times found related with petroleum. Natural gas is the main source of methane altogether with smaller quantities of C2 - C6 alkanes (that is, ethane, propane, butane, pentane and hexane). The alkanes are separated through fractional distillation. Whenever sulphur is present, it is oxidized to sulphur (VI) oxide, the precursor to H2SO4.
Petroleum or crude oil:
The fractional distillation of petroleum gives a broad range of alkanes. The C1 - C5 alkanes are as well obtained like in natural gas and the fractions of higher boiling points include mostly higher alkanes.
Vegetable Origin:
Methane is obtained as the product of anaerobic action on organic matter found buried in the earth or in sewages or in marsh gas and fire damp. Coal gas is obtained from the destructive distillation of natural coal includes around 30% methane.
Laboratory preparation of alkanes:
1) Heating anhydrous salts of alkanoic (organic) acids. The -CO2- group of alkanoic acid can be eliminated by heating the sodium salts of the alkanoic acid with soda lime (that is, a mixture of sodium and calcium hydroxides).
For illustration:
RCOONa+ + NaOH → RH + Na2CO3
CH3CO2Na + NaOH → CH4 + Na2CO3
Sodium ethanoate (from soda lime) methane
The methane gas is collected over the water.
2) Wurtz coupling - alkyl halides example: iodoalkanes can be coupled in the presence of the sodium metal to form alkanes, example:
2RI + 2Na → R-R + 2NaI
2CH3I + 2Na → CH3-CH3 + 2NaI
Ethane
Properties of Alkanes:
Physical properties:
1) The boiling and melting points of simple alkanes increase steadily as the number of carbon atoms rises due to the increasing strength of the van der waals forces and increase in the molecular mass. There is a gradation in crate from gas to liquid to solid as you move from lower to the higher members. Example: methane (CH4), is a gas, hexane (C6H12) is a liquid, dodecane C12H24 is a waxy solid.
2) All the alkanes are almost insoluble in water, and being less dense, the liquid and solid alkanes float on the surface of water. Example: hexane and dodecane. That is why water can't be employed for putting out petrol and oil fires. The lower members of the alkane series are soluble in the organic solvents.
Chemical Properties:
1) Combustion:
Alkanes burn in the ample supply of oxygen to form carbon (IV) oxide and water. This is as well characteristic of other hydrocarbons - ethene, ethyne and benzene. In limited supply of oxygen, carbon (II) oxide and water is formed rather.
CH4 + 2O2 → CO2 + 2H2O
2CH4 + 3O2 → 2CO + 4H2O (limited supply of oxygen)
2C2H6 + 7O2 → 4CO2 + 6H2O
The ease of burning accounts for the use of many alkanes as fuels.
2) Substitution Reactions:
One or more of the hydrogen atoms in the alkane can be substituted by the halogens (Cl, Br or I). The alkane reacts with chlorine, bromine or iodine in the presence of ultra-violet light or a temperature of around 400°C.
The reaction is halogenation (that is, addition of halogens) reaction and it is a substitution (substituting the hydrogen atom with the other element) method.
Fig: Substitution Reactions
(c) Cracking:
It is a significant industrial method used for breaking large hydrocarbon molecules to smaller ones. Alkanes experience industrially significant elimination reactions in which they lose hydrogen. The reaction needs a high temperature and, possibly, a catalyst. The products are generally unsaturated hydrocarbons (alkenes and alkynes) and at times soot (that is, carbon black) is formed.
C2H6 → 850oC → H2C = CH2 + H2
C3H8 → Cr2O3/Al2O3 catalyst → H3C - CH = CH2 + H2
2CH4 → 1500oC → HC ≡ CH + 3H2
Uses of Alkanes:
1) They are generally employed as fuels - butane gas and petrol.
2) Higher alkanes like paraffin wax is employed for candle manufacture, lubricants and so on.
3) Alkanes react by chlorine in the presence of light to give chloroalkanes example - chloroform, employed in hospitals as an 'Anaesthetic' agent, carbon tetrachloride employed as solvent for grease in dry cleaning and as well in the fire extinguishers.
Tutorsglobe: A way to secure high grade in your curriculum (Online Tutoring)
Expand your confidence, grow study skills and improve your grades.
Since 2009, Tutorsglobe has proactively helped millions of students to get better grades in school, college or university and score well in competitive tests with live, one-on-one online tutoring.
Using an advanced developed tutoring system providing little or no wait time, the students are connected on-demand with a tutor at www.tutorsglobe.com. Students work one-on-one, in real-time with a tutor, communicating and studying using a virtual whiteboard technology. Scientific and mathematical notation, symbols, geometric figures, graphing and freehand drawing can be rendered quickly and easily in the advanced whiteboard.
Free to know our price and packages for online chemistry tutoring. Chat with us or submit request at [email protected]
separation of peptides tutorial all along with the key concepts of protein purification, purification technique on the basis of solubility, purification technique on the basis of molecular size, kinds of gel materials
www.tutorsglobe.com offers Fifth Generation Language homework help, assignment help, case study, writing homework help, online tutoring assistance by computer science tutors.
www.tutorsglobe.com offers chemical reactivity homework help, chemical reactivity assignment help, online tutoring assistance, organic chemistry solutions by online qualified tutor's help.
tutorsglobe.com corolla assignment help-homework help by online perianth tutors
tutorsglobe.com plant physiology assignment help-homework help by online botany tutors
Theory and lecture notes of Functions and Graphs all along with the key concepts of functions and graphs, Lines in the Plane, Graphs and Graphing Utilities, Combinations of Functions, Inverse Functions. Tutorsglobe offers homework help, assignment help and tutor’s assistance on Functions and Graphs.
tutorsglobe.com bargaining theory of wages assignment help-homework help by online wages tutors
tutorsglobe.com classification of bryophyte assignment help-homework help by online bryophytes tutors
www.tutorsglobe.com offers modelling the system architecture homework help, assignment help, case study, writing homework help, online tutoring assistance by computer science tutors.
introduction to photochemistry tutorial all along with the key concepts of light-matter, absorption of light by atoms and molecules, photochemistry, basic laws of photochemistry, reaction pathways, applications of photochemistry, photochemistry induced by visible-ultraviolet light
tutorsglobe.com capital budgeting and project planning assignment help-homework help by online financial management tutors
Enthalpy changes tutorial all along with the key concepts of Enthalpy and enthalpy changes, Relationship between CP and CV of an ideal gas, Adiabatic expansion and Joule-Thomson effect
tutorsglobe.com fund flow analysis assignment help-homework help by online tools of financial analysis tutors
tutorsglobe.com the vasopressin assignment help-homework help by online metabolic functions of the growth hormone tutors
Theory and lecture notes of Reduction of Higher Order Equations to Systems all along with the key concepts of differential equations, motion of a pendulum, universal higher order equation. Tutorsglobe offers homework help, assignment help and tutor’s assistance on Reduction of Higher Order Equations to Systems.
1948869
Questions Asked
3689
Tutors
1487671
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!