What mass of carbon must be burned in order to increase


If anyone could help me, I would appreciate it very much. I havetwo questions that i'm having problems with. There isn't a textbookfor Environmental Chemistry on Cramster yet, but I was told theproblems are similar to those in Organic Chemistry? I'm notsure.

PROBLEMS
1. Calculate the concentration of SO2(ppm) that must bereached in polluted air (in ppm) if the dissolved gas is to producea pH of 4.4 in rain drops without any oxidation of the gas.

2. Taking the mass of the atmosphere to be 5.3E15 metric tons, what mass of carbon must be burned in order to increase the average carbon dioxide level in the atmosphere by 190ppm by volume (inmetric tons)?

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