Using linear algebra operations find the expectation value


Q1. (a) Show by direct evaluation that the eigenvectors of Pauli's σy matrix (in the representation of the eigenvectors |+) and |-) of σz)

100_Figure.png

is the y-component of the ½-spin operator in the same representation. That is, show, that |+y) and |-y) are eigenvectors of Sy with eigenvectors ± h/2.

(b) Give the numerical value of h/2 in J·s and in J·s/mol units, and (c) show that the SI units of position times linear momentum are also J·s.

Q2. Find the probability to measure Ss = + h/2 in:

(a) a ½-spin beam of particles polarized along the y direction with quantum state

|+y) =  1/√2 |+) + i/√2 |-)

and (b) in ½-spin beam of particles polarized in xz plane along an axis at an angle θ = 45o relative to the z-axis, with quantum state

|ψθ) = cos θ/2 |+) + sin θ/2 |-)

Express probabilities in percent units.

(c) Using linear algebra operations, find the expectation value of the spin along the z axis for the quantum state in (b)

(Sx)θ = (ψθ|Sxθ)

where

2324_Figure1.png

Express the results in SI units.

(d) Confirm that the result in (c) is consistent with the weighted average of the spin up and spin down states along the z axis:

(Sx)θ = h/2 p+ + (-(h/2))p-

where p+ and p- are, respectively, the probabilities to measure Sx = + h/2 and Sz = - h/2 in the quantum state in (b).

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Chemistry: Using linear algebra operations find the expectation value
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