The sulfide forms in preference to ag2o even though the


The black tarnish that forms on pure silver is the sulfide Ag2S, formed by reaction with H2S in the atmosphere:

4 Ag + 2 H2S + O2 2 Ag2S + 2 H2O

The sulfide forms in preference to Ag2O, even though the atmosphere is 20% O2 with just a trace of H2S. Explain this by selecting all that apply.

a. Formation of the sulfide is consistent with the HSAB principle.

b. Silver is a soft Lewis acid.

c. Oxygen is a hard Lewis base.

d. Silver is a hard Lewis acid.

e. Hydrogen sulfide is a soft Lewis base.

f. Hydrogen sulfide is a hard Lewis base.

g. Oxygen is a soft Lewis base.

h. Formation of the sulfide is not consistent with the HSAB principle.

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Chemistry: The sulfide forms in preference to ag2o even though the
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