The mass to use in the expression for the vibrational


The mass to use in the expression for the vibrational frequency of a diatomic molecule is the effective mass μ = mAmB/(mA + mB), where mA and mB are the masses of the individual atoms. The followingdata on the infrared absorption wavenumbers (wavenumbers in cm-1) of molecules are taken from Spectra of diatomic molecules, G. Herzberg, van Nostrand (1950):

H35Cl H81Br HI CO NO

2990 2650 2310 2170 1904

Calculate the force constants of the bonds and arrange them in order of increasing stiffness.

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Chemistry: The mass to use in the expression for the vibrational
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