Measure of the result of an adiabatic joule free expansion


Response to the following problem:

(a) A measure of the result of an adiabatic Joule free expansion is provided by the louie coefficient η = (∂T/∂V)U .

Show that η = - (1/CV) ((βT/k) - P) .

(b) A measure of the result of the Joule-Thomson expansion (adiabatic throttling process or isenthalpic expansion) is provided by the Joule- Thomson coefficient  η = (∂T/∂P)H .

Show that η = - V/CP (βT - 1) .

 

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Chemistry: Measure of the result of an adiabatic joule free expansion
Reference No:- TGS02045266

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