In developing the fundamental equation from the first and


1. In developing the fundamental equation from the first and second laws, we have neglected gravitational, electrical, and surface effects. Surface effects may be taken into account by: dG= -SdT + VdP + ydA where y is the interfacisl tension and A is the interfacial area.

a. Write y as a partial derivative of G.

b. Given a new variable defined as ?= G -yA use the Legendre Transform to transform the fundamental equation from G(T,P,A) to ?(T,P,y).

c. Write a two Maxwell like relations using y as a dependent variable.

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Other Subject: In developing the fundamental equation from the first and
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