Explain pure lead freezes at one constant temperature of, Chemistry

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Explain pure lead freezes at one constant temperature of

(a) Explain pure lead melts at 327oC and pure tin melts at 232o C, yet while we make an alloy of lead-61.9 wt% Sn it melts at a much lower temperature of 183oC, explain.

(b) Explain pure lead freezes at one constant temperature of 327oC, yet the lead- 30 wt% Sn alloy freezes over a 60 oC temperature range, explain.

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