33. A coffee cup calorimeter is used to determine the specific heat of a metallic sample. The calorimeter is filled with 50.0 mL of water at 25.0°C (density of water = 0.997 g/mL). A 36.5 g sample of the metal is taken from a boiling water bath at 100.0°C and placed in the calorimeter. The equilibrium temperature of the water and sample is 32.5°C. The calorimeter constant is 1.87 J/°C. Calculate the specific heat of the metal sample.
a) 0.62 J/g•°C
b) 0.63 J/g•°C
c) 0.66 J/g•°C
d) 0.64 J/g•°C