A 10g sample containing an analyte was transferred to a 250 mL flask and diluted to volume. A 10mL aliquot of this solution, diluted to 25mL, yielded a signal of .235 units. A second 10 mL aliquot was spiked with 10mL of 1ppm standard solution of the analyze and diluted to 25mL. The signal for the spiked sample was .502 units. What is the wt% of analyze in the original sample