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The porphyry in molecule has 26 π electrons. Many proteins contain metal porphyry in molecules. This molecule is planar, and so we can approximate the π electrons as being confined inside a sq
How could you use a precipitation reaction to separate the two metal ions? Assume that you have an aqueous solution of CuCl2and BaCl2.
The rate of the reaction if found to be directly proportional to the concentrations of H,+ benzaldehyde and MnO4. Benzaldehyde (C6H5CHO) is oxidized to benzoic acid by potassium permanganate in acid
Discuss how is a particular wave length at which to make the absorbance measurements chosen? How can determine the oxidation number of Co in the complex ion [Co(en)2Br2]+?
To make 31.90 mL of solution a 0.6370-g sample of impure Ca (OH)2 is dissolved in the enough water. 20.00 mL of the resulting solution is then titrated with the 0.2593-M HCl.
The final solution has a volume of 0.25000 dm3, and a concentration of 0.248 mol dm-3, if pure liquid bromine has a molar mass of 159.808 g, a solution of bromine water is prepared for use in the labo
An element Z produces both a tetrachloride (ZCl4) and adichloride (ZCl2). Treatment of 10.00 g ZCl2 with excess chlorine produces the12.55 g of ZCl4. Determine the atomic mass of Z.
The density of monoclinic sulfur is 1.96 g/cm3. The density of rhombic sulfur is 2.07 g/cm3. Both allotropic solid produces of sulfur consist of the discrete cyclic S8molecules. Explain w
The rhombic Sis all converted to monoclinic S (density 1.96g/cm3) to get a volume of4.22cm3 monoclinic S. 8.28g of rhombic S (density 2.07g/cm3) occupies 4 cm3.
A test bar 12.83 mm in dia. with a 50-mm gage length is loaded axially with the 200 kN (45,000lb) and is stretched 0.458 mm (0.018 in) Its diameter is 12.79 mm (.5035 in) under load.
Explain how much load can a 2.74-mm (.108-in) wire of this alloy support without yielding? What is the total extension if a load of 55 kg (121lb) is supported by a 30.5-m (100-ft) wire of this size.
Sketch the energy, in the form of the ATP, that is lost and gained during the metabolism of one (1) glucose molecule through the Kreb's cycle, glycol sis, and the electron transport c
Explain how deep will a crack be before the steel is subject to fracture as a mode of failure? A steel with a Kic value of 190 MPa*m^(1/2) also has a yield strength of 900 MPa.
The fermentation of fruit juice to produce wine involves the conversions of glucose (C6H12O6) to carbon dioxide and ethanol (C2H6O).
The expansion can occur via any one of four different paths: a) isothermal and reversible, b) isothermal and irreversible, c) adiabatic and reversible, and d) adiabatic and irreversible.
Determine the radius of a silver atom in nm when the Silver metal crystals have an FCC (face centered cubic crystals) structure. The unit cell edge in silver is 0.4086 nm long.
At 0o C the solubility of caffeine in water is 0.022 g/mL. This means that for every mL of water, 0.022 g of caffeine will dissolve. A student wanted to separate a heterogeneous mixture which i
Calcium carbide reacts with the water to form the calcium hydroxide and acetylene. Determine the volume of acetylene (C2H2) produced at the 25oC and 0.95 atm pressure found by the reaction of 45 grams
What volume of gas will be produced in the person's stomach when swallowed at body temperature (36°C) and a pressure of 3 atm when the O2 has density 1.149 g/mL and the volume of 0.060 mL.
Determine the numbers of moles of benzoic acid will be left behind in the organic layer after this extraction step? Assume a solution of 0.5g of benzoic acid in the dichloromethane is treated with
A U-tube containing mercury metal is used to determine the density of unknown oil. When a height of 54 cm of oil is poured in the tube, the difference in height of the two levels of the mercury
When you calibrated the same gel filtration column, the elution volumes of proteins of known molecular weights were as follows: 400,000 Da, 10 ml; 250,000Da, 20 ml; 150, 000 Da, 30 ml; 100,000 Da, 4
Explain how would you determine the work of reversible, isothermal expansion from Vi to Vf for a gas that follows the equation of state: P(V - nb) = nRT
Calculate the total number of ways that the five distinguishable marbles can be distributed in two different boxes and identify which is the most probably distribution.
The clay impurity loses 11% of its weight as moisture on prolonged heating. 5g of chalk on heating shows a loss in weight (due to evolution ofCO2 and water) by 1.1g. A sample of chalk contains