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  Gluconeogenesis of Glycerol

Gluconeogenesis of Glycerol:

At starvation time glycerol can as well go through gluconeogenesis. While the triglycerides are hydrolysed in the adipose tissue, glycerol is released. Additional metabolism of glycerol does not occur in the adipose tissue due to the lack of glycerol kinase essential to phosphorylate it. In its place, glycerol passes to the liver in which it is phosphorylated to glycerol 3-phosphate via the enzyme glycerol kinase.

Glycerol + ATP (Glycerol kinase) → Glycerol 3-phosphate + ADP

This type of pathway connects the triose phosphate stage of glycolysis, since glycerol 3-phosphate is oxidized to dihydroxy acetone phosphate in the existence of NAD+ and glycerol 3-phosphate dehydrogenase.

Glycerol 3-phosphate  ( Glycerol 3-phosphate) → Dihydroxy acetone phosphate + NADH + H+
    + NAD+                          dehydrogenase                                    
                                                                                                                                
                 
This dihydroxy acetone phosphate comes in gluconeogenesis pathway and gets transformed to glucose. Liver and kidney are capable to convert glycerol to blood glucose via utilize the above enzymes.

 

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