What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
order of decreasing basicity of urea and its substituents
why allyl halide and haloarenes are more reactive than alkyl halide towards nucleophilic substitution
Choose the right answer from following. The magnitude of colligative properties in all colloidal dispersions is : (a) Lowerthan solution (b)Higher than solution(c) Both (d) None
Choose the right answer from following. Colligative properties are used for the determination of: (a) Molar Mass (b) Equivalent weight (c) Arrangement of molecules (d) Melting point and boiling point (d) Both (a) and (b)  
In zinc blende structure, zinc atom fill up:(a) All octahedral holes (b) All tetrahedral holes (c) Half number of octahedral holes (d) Half number of tetrahedral holesAnswer: (d) In zinc blende (ZnS
Which one of the following pairs of solutions can we expect to be isotonic at the same temperature:(i) 0.1M Urea and 0.1M Nacl (ii) 0.1M Urea and 0.2M Mgcl2 (iii) 0.1M Nacl and 0.1M Na2SO4 (iv) 0.1M Ca(NO3<
The first method begins with a well defined layer, or boundary, of solution near the center of rotation and tracks the movement of this layer to the outside of the cell as a function of time. Such a method is termed a sedimentary velocity experiment. A
Presence of small concentrations of appropriate electrolyte is necessary to stabilize the colloidal solutions. However, if the electrolytes are present in higher concentration, then the ions of the electrolyte neutralize the charge on the colloidal particles may unite
Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid, establishes a buffer with a pH of approximately 5.
Give me answer of this question. The vapour pressure of benzene at a certain temperature is 640mm of Hg. A non-volatile and non-electrolyte solid weighing 2.175g is added to 39.08g of benzene. The vapour pressure of the solution is 600,mm of Hg . What is the mo
18,76,764
1932027 Asked
3,689
Active Tutors
1428162
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!