What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
When 0.01 mole of sugar is dissolved in 100g of a solvent, the depression in freezing point is 0.40o. When 0.03 mole of glucose is dissolved in 50g of the same solvent, depression in the freezing point will be:(a) 0.60o (b) 0.80o
What will be the molality of a solution containing 18g of glucose (having mol. wt. = 180) dissolved in 500g of water: (i) 1m (ii) 0.5m (iii) 0.2m (iv) 2m
Provide solution of this question. Which has maximum vapour pressure: (a) HI (b) HBr (c) HCl (d) HF
Choose the right answer from following. Which one of the following is an extensive property: (a) Molar volume (b) Molarity (c) Number of moles (d) Mole fraction
Vapour pressure of methanol in water Give me answer of this question. An aqueous solution of methanol in water has vapour pressure: (a) Equal to that of water (b) Equal to that of methanol (c) More than that of water (d) Less than that of water
Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer.
arrange in order of basicity,pyridine,pipyridineand pyorine
lculwhat is the equation for caating molar mass of non volatile solute
Nucleophilic substitution reactions in halides containing - X bond may take place through either of the two different mechanisms,S<
The molarity of 0.006 mole of NaCl in 100 solutions will be: (i) 0.6 (ii) 0.06 (iii) 0.006 (iv) 0.066 (v) None of theseChoose the right answer from above.Answer: The right answer is (ii) M = n/ v(
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