What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Karl Scheele, the Swedish chemist, was
The diazonium salts are represented by the general formula ArN2 +X where X- ion may be anion such as (Cl) ¨, B ¨r, HSO
What do you mean by the term alum? Also illustrate its uses?
what are condensation polymerization give in with 2 examples
Write a short note on the IUPAC name of the benzene?
What volume of solution contains 0.1 mole of the solute: (a) 100ml (b) 125ml (c) 500ml (d) 62.5ml Choose the right answer from above.
The weight of pure NaOH needed to made 250cm3 of 0.1 N solution is: (a) 4g (b) 1g (c) 2g (d) 10g Choose the right answer from above.
Choose the right answer from following. The number of moles of KCL in 1000ml of 3 molar solution is: (a)1 (b)2 (c)3 (d)1.5
Illustrate all the explosions produce carbon dioxide?
Describe briefly the procedure to judge that the given organic compound is pure or not?
18,76,764
1936978 Asked
3,689
Active Tutors
1461350
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!