What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Avogadro's hypothesis Law Principle- Berzelius, a chemist tried
Among the below shown which crystal will be soft and have low melting point: (a) Covalent (b) Ionic (c) Metallic (d) MolecularAnswer: (d) Molecular crystals are soft and have low melting point.
The various elements
The bonding in ionic molecules can be described with a coulombic attractive term.For some diatomic molecules we take quite a different approach from that used in preceding sections to describe the bonding. Ionic bonds are interpreted in terms of the coulom
Normal 0
what is the equation for calculating molar mass of non volatile solute
Describe the various cons of eating the organic foods? Briefly illustrate it.
Choose the right answer from following.The relative lowering of the vapour pressure is equal to the ratio between the number of: (a) Solute moleules and solvent molecules (b) Solute molecules and the total molecules in the solution (c) Solvent molecules and the tota
Explain the method, how do you solve Ideal Gas Law problems?
An experiment to determine the convection coefficient associated with airflow over the surface of a thick stainless steel casting involves insertion of thermocouples in the casting at distances of 10 mm and 20 mm from the surface. When the experiment was perform
18,76,764
1948523 Asked
3,689
Active Tutors
1454217
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!