What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Like ammonia, primary, secondary and tertiary amines have a single pair of electrons on N atom. Hence chemical behavior of amines is similar to ammonia. Amines are basic in nature, and in most of the reactions they act as nucleophiles. 1. Reaction wi
The freezing point of a solution having 4.8 g of a compound in 60 g of benzene is 4.48. Determine the molar mass of the compound (Kf = 5.1 Km-1) , (freezing point of benzene = 5.5oC) &n
Give me answer of this question. If 20ml of 0.4N, NaoH solution completely neutralises 40ml of a dibasic acid. The molarity of the acid solution is:(a) 0.1M (b) 0.2M (c)0.3M (d)0.4M
Drugs are broadly classified into following types depending on the purpose for which they are used. 1. Antipyretics
density of water is 1g/mL.The concentration of water in mol/litre is
Choose the right answer from following.The relative lowering of the vapour pressure is equal to the ratio between the number of: (a) Solute moleules and solvent molecules (b) Solute molecules and the total molecules in the solution (c) Solvent molecules and the tota
Provide solution of this question. Unit of mole fraction is: (a) Moles/litre (b) Moles/litre2 (c) Moles-litre (d) Dimensionless
Atomic orbitals can be combined, in a process called hybridization, to describe the bonding in polyatomic molecules. Descriptions of the bonding in CH4 can be used to illustrate the valence bond procedure. We must arrive a
Give me answer of this question. When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is equal to: (a) Mole fraction of solute (b) Mole fraction of solvent (c) Concentration of the solute in grams per litre (d) Concentratio
Illustrate how are dipole attractions London dispersion forces and hydrogen bonding similar?
18,76,764
1935724 Asked
3,689
Active Tutors
1417012
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!