What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Choose the right answer from following. Which one of the statements written below concerning properties of solutions, explain a colligative effect: (a) Boiling point of pure water decreases by the addition of ethano (b) Vapour pressure of pure water d
Give me answer of following question. The sum of the mole fraction of the components of a solution is : (a) 0 (b) 1 (c) 2 (d) 4.
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Integration of the second order rate equations also produces convenient expressions for dealing with concentration time results.A reaction is classified as second order if the rate of the reaction is proportional to the square of the concentration of one o
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Can someone please help me in getting through this problem. The total number of molecules in 16 gm of methane will be: (i) 3.1 x 1023 (ii) 6.02 x 1023 (iii) 16/6.02 x 1023 (iv) 16/3.0 x 1023
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These types of polymers are formed as a result of condensation reaction between monomer units. Some common examples are being discussed here: 1. Polyesters Q : Mole fraction of Carbon dioxide Choose Choose the right answer from following. If we take 44g of CO2 and 14g of N2 what will be mole fraction of CO2 in the mixture: (a) 1/5 (b) 1/3 (c) 2/3 (d) 1/4
Choose the right answer from following. If we take 44g of CO2 and 14g of N2 what will be mole fraction of CO2 in the mixture: (a) 1/5 (b) 1/3 (c) 2/3 (d) 1/4
Choose the right answer from following. Molar concentration (M) of any solution : a) No. of moles of solute/Volume of solution in litre (b) No. of gram equivalent of solute / volume of solution in litre (c) No. of moles os solute/ Mass of solvent in kg (
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