What is cannizaro reaction? Explain with example.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example, It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Aldehydes which do not have -hydrogen atom, such as formaldehyte and benzaldehyte, when heated with concentrated (50%)alkali solution, give a mixture of alcohol and the salt of a carboxylic acid. In this reaction, the aldehyde undergoes disproportionate. It implies that one molecule of aldehydes is oxidized to carboxylic acid and the other is reduced to alcohol. Ketones do not provide this reaction. The reaction is also possible in all compounds which lack -hydrogen atom. For example,
It must be noted that in crossed Cannizzaro's reaction, when an aldehydes is treated with formaldehyde and aqueous basic solution then it is formaldehyde that undergoes oxidation. Compounds containing two carbonyl groups undergo internal Cannizzaro's reaction. On the other hand, aldehydes containing -hydrogen atoms when heated with concentrated alkali give brown resinous mass.
Give me answer of this question. The vapour pressure of water at 20degreeC is 17.54 mm. When 20g of a non-ionic, substance is dissolved in 100g of water, the vapour pressure is lowered by 0.30 mm. What is the molecular weight of the substances: (a) 210.2 (b) 206.88
Benzene and toluene form nearly ideal solutions. At 20°C, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The parial vapour pressure of benzene at 20°C for a solution containing 78g of benzene and 46g of toluene in torr is: (a) 50 (b)
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The catalytic dehydrogenation of 1-butene to 1,3-butadiene, C4H8(g) = C4H6(g)+H2(g) is carried out at 900 K and 1 atm. Discover Q & A Leading Solution Library Avail More Than 1435065 Solved problems, classrooms assignments, textbook's solutions, for quick Downloads No hassle, Instant Access Start Discovering 18,76,764 1922208 Asked 3,689 Active Tutors 1435065 Questions Answered Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!! Submit Assignment
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