What are homogenous catalyst? Give few examples.
When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are: SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst. Oxidization of CO by O2 in the presence of NO as catalyst. Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst Hydrolysis of esters using H2SO4 as catalyst Hydrolysis of sucrose in the presence of dilute sulphuric acid. Mechanism of homogeneous catalysis As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2. In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.
The Van't Hoff factor of the compound K3Fe(CN)6 is: (a) 1 (b) 2 (c) 3 (d) 4 Answer: (d) K3[Fe(CN)6] → 3K+
Choose the right answer from following. The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of the substance will be: (a) 18.0 (b) 342 (c) 60 (d) 180
Illustrate how are dipole attractions London dispersion forces and hydrogen bonding similar?
Can someone please help me in getting through this problem. How many grams of dibasic acid (having mol. wt. 200) must be present in 100ml of its aqueous solution to provide decinormal strength: (i) 1g (ii)2g (iii) 10g (iv) 20g<
The methods used for the preparation of phenols are given below: From aryl sulphonic acids
lculwhat is the equation for caating molar mass of non volatile solute
Choose the right answer from following. An ideal solution was obtained by mixing methanol and ethanol. If the partial vapour pressure of methanol and ethanol are 2.619KPa and 4.556KPa respectively, the composition of the vapour (in terms of mole fraction) will be: (
During the formation of polymers, different macromolecules have different degree of polymerisation i.e. they have varied chain lengths. Thus, the molecular masses of the individual macromolecules in a particular sample of the polymer are different. Hence, an average value of the molecular mass is
Give me answer of this question. A solution contains 25%H2O 25%C2H5OH , and 50% CH3 COOH by mass. The mole fraction of H2O would be: (a) 0.25 (b) 2.5 (c) 0.503 (d) 5.03.
why BiF3 is ionic whereas other trihalides are covalent in nature?
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