What are homogenous catalyst? Give few examples.
When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are: SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst. Oxidization of CO by O2 in the presence of NO as catalyst. Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst Hydrolysis of esters using H2SO4 as catalyst Hydrolysis of sucrose in the presence of dilute sulphuric acid. Mechanism of homogeneous catalysis As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2. In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.
The acid value definition is the number milligrams of KOH needed to neutralize the acid present in one gram oil and fats however why not employ NaOH for the neutralization?
Elaborate a substituted hydrocarbon?
Give me answer of this question. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of the pure hydrocarbons at 20°C are 440 mmHg for pentane and 120 mmHg for hexane. The mole fraction of pentane in the vapour phase would be: (a) 0.549 (b)
Write down a short note on the differences between the organic and inorganic chemistry?
Normal butane (C4H10) is stored as a compressed liquid at 90°C and 1400 kPa. In order to use the butane in a low-pressure gas-phase process, it is throttled to 150 kPa and passed through a vaporizer. The butane emerges from the vaporizer as a
Provide solution of this question. In an experiment, 1 g of a non-volatile solute was dissolved in 100 g of acetone (mol. mass = 58) at 298K. The vapour pressure of the solution was found to be 192.5 mm Hg. The molecular weight of the solute is (vapour pressure of ace
The thermal part of the internal energy and the enthalpy of an ideal gas can be given a molecular level explanation. All the earlier development of internal energy and enthalpy has been "thermodynamic". We have made no use o
The integrated forms of the first order rate equations are conveniently used to compare concentration time results with this rate equation. Rate equations show the dependence of the rate of the reaction on concentration can be integrated to give expressions fo
Why oxidising character of oxoacids of halogens decreases as oxidation number increases?
Provide solution of this question. Unit of mole fraction is: (a) Moles/litre (b) Moles/litre2 (c) Moles-litre (d) Dimensionless
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