--%>

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Molarity of the final mixture Can

    Can someone please help me in getting through this problem. Two solutions of a substance (that is, non electrolyte) are mixed in the given manner 480 ml of 1.5M first solution + 520 ml of 1.2M second solution. Determine the molarity of the final mixture

  • Q : Problem based on normality Choose the

    Choose the right answer from following. NaClO solution reacts with H2SO3 as,. NaClO + H2SO3→NaCl+ H2SO4. A solution of NaClO utilized in the above reaction contained 15g of NaClO per litre. The

  • Q : What is electrolytic dissociation? The

    The Debye Huckel theory shows how the potential energy of an ion in solution depends on the ionic strength of the solution.Except at infinite dilution, electrostatic interaction between ions alters the properties of the solution from those excepted from th

  • Q : Explain reactions of carbonyl oxygen

    In these reaction oxygen atom of carbonyl group is replaced by either one divalent group or two monovalent groups. Reaction by ammonia derivatives: aldehydes and ketones react with a number of ammonia derivatives such as hydroxylaminem hydrazine, semicarbazide etc. in weak acidic medium.

  • Q : Normality of sulphuric acid Help me to

    Help me to go through this problem. Normality of sulphuric acid is: (a) 2N (b) 4N (c) N/2 (d) N/4

  • Q : Organic and inorganic substances living

    living beings are made up of organic and inorganic substances.according to their complexity of their molecules how can ach of these substances be classified?

  • Q : BASIC CHARACTER OF AMINES IN GAS PHASE,

    IN GAS PHASE, BASICITIES OF THE AMINES IS JUST OPPOSITE TO BASICITY OF AMINES IN AQEUOUS PHASE .. EXPLAIN

  • Q : Question based on maximum vapour

    Provide solution of this question. Which has maximum vapour pressure: (a) HI (b) HBr (c) HCl (d) HF

  • Q : Which is polar HCl or HF Which one is

    Which one is polar HCl or HF?

  • Q : Explain preparation and properties of

    It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2    4