--%>
Assignment Help - homework help

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Biodegradable polymers what are the

    what are the examples of biodegradable polymers

    		•
  • Q : Lowering of vapour pressure Help me to

    Help me to go through this problem. Lowering of vapour pressure is highest for: (a) urea (b) 0.1 M glucose (c) 0.1M MgSo4 (d) 0.1M BaCl2

    		•
  • Q : What are methods of phenol preparation

    Phenol was initially obtained by fractional distillation of coal

    		•
  • Q : Explain Second Order Rate Equations.

    Integration of the second order rate equations also produces convenient expressions for dealing with concentration time results.A reaction is classified as second order if the rate of the reaction is proportional to the square of the concentration of one o

    		•
  • Q : Molality of Sulfuric acid Choose the

    Choose the right answer from following. The molality of 90% H2SO4 solution is: [density=1.8 gm/ml]  (a)1.8 (b) 48.4 (c) 9.18 (d) 94.6

    		•
  • Q : Pressure Phase Diagrams The occurrence

    The occurrence of different phases of a one component system can be shown on a pressure temperature. The phases present in a one line system at various temperatures can be conveniently presented on a P- versus-T diagram. An example is pro

    		•
  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b

    		•
  • Q : Molar conductance what is the molar

    what is the molar conductance of chloropentaamminecobalt(III) chloride?

    		•
  • Q : Electrochemistry ( electrolysis of

    1. Define Faraday's first law of electrolysis 2. define Faraday's second law of electrolysis

    		•
  • Q : Molecular basis of third law. The

    The molecular, or statistical, basis of the third law can be seen by investigating S = k in W.The molecular deductions of the preceding sections have led to the same conclusions as that stated in the third law of thermodynamics, namely, that a value can be

    		•