--%>

Problem on reversible process

a. For a reversible process involving ideal gases in a closed system, Illustrate that

ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process

b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed vessel to a temperature of 368 K. Taking specific heat at constant volume to be 1.42 KJ/Kg.K

c. Compute the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature remains constant.

d. What is the change in entropy when 1 kmol of an  ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? Cp = 29.3 KJ/(kmol K)

   Related Questions in Chemistry

  • Q : Molecular weight of solute Select right

    Select right answer of the question. A dry air is passed through the solution, containing the 10 gm of solute and 90 gm of water and then it pass through pure water. There is the depression in weight of solution wt by 2.5 gm and in weight of pure solvent by 0.05 gm. C

  • Q : What is adsorption and its examples. In

    In a liquid a solid substance a molecule present within the bulk of the substance is being attracted infirmly from all sides by the neighbouring molecules. Hence there is no bet force acting on the molecule or there are no unbalanced forces of the molecule. On the oth

  • Q : Molecular mass from Raoults law Provide

    Provide solution of this question. Determination of correct molecular mass from Raoult's law is applicable to: (a) An electrolyte in solution (b) A non-electrolyte in a dilute solution (c) A non-electrolyte in a concentrated solution (d) An electrolyte in a liquid so

  • Q : Colligative effect Choose the right

    Choose the right answer from following. Which one of the statements written below concerning properties of solutions, explain a colligative effect: (a) Boiling point of pure water decreases by the addition of ethano (b) Vapour pressure of pure water d

  • Q : Relative lowering in vapour pressure of

    Give me answer of this question. "Relative lowering in vapour pressure of solution containing non-volatile solute is directly proportional to mole fraction of solute". Above statement is: (a) Henry law (b) Dulong and Petit law (c) Raoult's law (d) Le-Chatelier's pri

  • Q : Reducible Representations The number of

    The number of times each irreducible representation occurs in a reducible representation can be calculated.Consider the C2v point group as described or Appendix C. you can see that (1) sum of

  • Q : What is schrodinger wave equation? The

    The Schrodinger wave equation generalizes the fitting-in-of-waves procedure.The waves that "fit" into the region to which the particle is contained can be recognized "by inspection" only for a few simple systems. For other problem a mathematical procedure

  • Q : Real vapour pressure Choose the right

    Choose the right answer from following. The pressure under which liquid and vapour can coexist at equilibrium is called the : (a) Limiting vapour pressure (b) Real vapour pressure (c) Normal vapour pressure (d) Saturated vapour pressure

  • Q : Calculate molarity of a solution

    Provide solution of this question. Molarity of a solution prepared by dissolving 75.5 g of pure KOH in 540 ml solution is: (a) 3.05 M (b) 1.35 M (c) 2.50 M (d) 4.50 M

  • Q : What do you mean by the term tripod

    What do you mean by the term tripod? Also state its uses?