Explain preparation and properties of phosphorus trichloride
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4OCl3 + 4SO2 + 2S2Cl2 Lab. Method: it is more conveniently prepared in the laboratory by heating white phosphorus in a current of dry chlorine when phosphorus trichloride distils over.P4 + 6Cl2 4PCl3Phosphorus is gently heated in a retort on a water bath and current dry chlorine is passed. Phosphorus trichloride distils over and is collected in a receiver cooled in freezing mixture.It is redistilled over white phosphorus to remove any phosphorus pentachloride present an impurity.Properties It is colourless fuming liquid. It reacts violently with water forming phosphorus acid.PCl3 + 3HOH H3PO3 + 3HCl It reacts with concentrated H2SO4 forming chlorosulphonic acid. Or, 2H2SO4 + PCl3 HSO3Cl + HPO3 + SO2 + HCl It reacts with organic compounds containing hydroxyl group. It directly combines with Cl2, O2 and S. this indicates that it is an unsaturated compound.PCl3 + Cl2 PCl52PCl3 + O2 2POCl3PCl3 + S PSCl3 It acts as a reducing agent.PCl3 + SO2Cl2 PCl5 + SO2PCL3 + SO3 POCL3 + SO23PCl3 + S2Cl2 PCL5 + 2PSCl3It reacts with finely divided metals when hot.12Ag + 4PCl3 12AgCl + P46Na + PCl3 3NaCl + Na2P
The occurrence of different phases of a one component system can be shown on a pressure temperature. The phases present in a one line system at various temperatures can be conveniently presented on a P- versus-T diagram. An example is pro
Can someone please help me in getting through this problem. The total number of molecules in 16 gm of methane will be: (i) 3.1 x 1023 (ii) 6.02 x 1023 (iii) 16/6.02 x 1023 (iv) 16/3.0 x 1023
In some two component, solid liquid systems, a eutectic mixture forms.Consider, now a two component system at some fixed pressure, where the temperature range treated is such as to include formation of one or more solid phases. A simple behavior is shown b
Integration of the second order rate equations also produces convenient expressions for dealing with concentration time results.A reaction is classified as second order if the rate of the reaction is proportional to the square of the concentration of one o
1. Physical state: the first three aliphatic acids are colourless liquids with pungent smell. The next six are oily liquids with an odour of rancid butter while the higher members are colourless, odourless waxy solids. Benzoic acid is referred to
The pressure-temperature relation for solid-vapor or liquid vapor equilibrium is expressed by the Clausis-Clapeyron equation.We now obtain an expression for the pressure-temperature dependence of the state of equilibrium between two phases. To be specific,
Emulsions are colloidal solutions in which disperse phase as well as dispersion medium is both liquids. Emulsions can be broadly classified into two types: (i) Oil in water (O/W type) emulsions: in this type of emulsions, oil acts disperse phase and water acts
Ideal mixing properties can be recognized in the formation of an ideal gas mixture from ideal gases. Consider the formation of a mixture of gases i.e. a gaseous solution, from two mixtures of pure gases. A useful characterization of an ideal mixture, or soluti
Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid, establishes a buffer with a pH of approximately 5.
Choose the right answer from following. An aqueous solution of glucose is 10% in strength. The volume in which mole of it is dissolved will be : (a) 18 litre (b) 9 litre (c) 0.9 litre (d) 1.8 litre
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