Explain preparation and properties of phosphorus trichloride
It may be prepared by the action of phosphorus on thionyl chloride.P4 + 8SOCl2 4OCl3 + 4SO2 + 2S2Cl2 Lab. Method: it is more conveniently prepared in the laboratory by heating white phosphorus in a current of dry chlorine when phosphorus trichloride distils over.P4 + 6Cl2 4PCl3Phosphorus is gently heated in a retort on a water bath and current dry chlorine is passed. Phosphorus trichloride distils over and is collected in a receiver cooled in freezing mixture.It is redistilled over white phosphorus to remove any phosphorus pentachloride present an impurity.Properties It is colourless fuming liquid. It reacts violently with water forming phosphorus acid.PCl3 + 3HOH H3PO3 + 3HCl It reacts with concentrated H2SO4 forming chlorosulphonic acid. Or, 2H2SO4 + PCl3 HSO3Cl + HPO3 + SO2 + HCl It reacts with organic compounds containing hydroxyl group. It directly combines with Cl2, O2 and S. this indicates that it is an unsaturated compound.PCl3 + Cl2 PCl52PCl3 + O2 2POCl3PCl3 + S PSCl3 It acts as a reducing agent.PCl3 + SO2Cl2 PCl5 + SO2PCL3 + SO3 POCL3 + SO23PCl3 + S2Cl2 PCL5 + 2PSCl3It reacts with finely divided metals when hot.12Ag + 4PCl3 12AgCl + P46Na + PCl3 3NaCl + Na2P
The number of molecular orbitals and molecular motions of each symmetry type can be deduced. Let us continue to use the C2v point group and the H2O molecule to illustrate how the procedure develop
Choose the right answer from following. An X molal solution of a compound in benzene has mole fraction of solute equal to 0.2. The value of X is: (a)14 (b) 3.2 (c) 4 (d) 2
Describe the net charge of a non-ionized atom?
Which is not a colligative property: (a) Refractive index (b) Lowering of vapour pressure (c) Depression of freezing point (d) Elevation of boiling point
What do you mean by the term dipole moment? Briefly describe it.
The boiling point of 0.1 molal aqueous solution of urea is 100.18oC at 1 atm. The molal elevation constant of water is: (a) 1.8 (b) 0.18 (c) 18 (d) 18.6Answer: (a) Kb
The molarity of 0.006 mole of NaCl in 100 solutions will be: (i) 0.6 (ii) 0.06 (iii) 0.006 (iv) 0.066 (v) None of theseChoose the right answer from above.Answer: The right answer is (ii) M = n/ v(
The amount of KMnO4 required to prepare 100 ml of 0.1N solution in alkaline medium is: (a) 1.58 gm (b) 3.16 gm (c) 0.52 gm (d) 0.31 gmAnswer: (a) In alkaline medium KMnO4 act as ox
Write down a short note on the differences between the organic and inorganic chemistry?
an atom of an element is 10.1 times heavier than the mass of a carbon atom.What is its mass in amu?
18,76,764
1932841 Asked
3,689
Active Tutors
1419965
Questions Answered
Start Excelling in your courses, Ask an Expert and get answers for your homework and assignments!!