--%>
Assignment Help - homework help

What are homogenous catalyst? Give few examples.

When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are:
    
SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst.

2141_homogenous catalyst.png 
    
Oxidization of CO by O2 in the presence of NO as catalyst.

1497_homogenous catalyst1.png 
    
Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst

1588_homogenous catalyst2.png 
    
Hydrolysis of esters using H2SO4 as catalyst

2088_homogenous catalyst3.png 
    
Hydrolysis of sucrose in the presence of dilute sulphuric acid.

84_homogenous catalyst4.png 

Mechanism of homogeneous catalysis 

As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2.
 
In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.

1574_homogenous catalyst5.png

   Related Questions in Chemistry

  • Q : Number of moles of potassium chloride

    Choose the right answer from following. The number of moles of KCL in 1000ml of 3 molar solution is: (a)1 (b)2 (c)3 (d)1.5

    		•
  • Q : Lowering of vapour pressure Help me to

    Help me to go through this problem. Lowering of vapour pressure is highest for: (a) urea (b) 0.1 M glucose (c) 0.1M MgSo4 (d) 0.1M BaCl2

    		•
  • Q : What is schrodinger wave equation? The

    The Schrodinger wave equation generalizes the fitting-in-of-waves procedure.The waves that "fit" into the region to which the particle is contained can be recognized "by inspection" only for a few simple systems. For other problem a mathematical procedure

    		•
  • Q : Molar and Volumetric flow rate problem

    Cyclohexane (C6H12) is produced by mixing Benzene and hydrogen. A process including a reactor, separator, and recycle stream is used to produce Cyclohexane. The fresh feed contains 260L/min C6H6 with 950 L/min of H2

    		•
  • Q : What are Vander Waal's Radii? Vander

    Vander Waal's radii can be assigned to the atoms of molecules on the basis of the closeness of approach of these atoms in crystalline substances. Diffraction studies of crystals give information about hoe molecules can approach each other and can pack

    		•
  • Q : Inorganic Chemistry Inorganic

    Inorganic Chemistry:In the year 1869, Russian Chemist Dmitry Mendeleyev forms the periodic table of the element. Since Newlands did before him in the year 1863, Mendeleyev categorizes the el

    		•
  • Q : Maximum vapour pressure Provide

    Provide solution of this question. Which solution will show the maximum vapour pressure at 300 K: (a)1MC12H22O11 (b)1M CH3 COOH (c) 1MNacl2 (d)1MNACl

    		•
  • Q : Cations Chromium(III) hydroxide is

    Chromium(III) hydroxide is highly insoluble in distilled water but dissolves readily in either acidic or basic solution. Briefly explain why the compound can dissolve in acidic or in basic but not in neutral solution. Write appropriate equations to support your answer

    		•
  • Q : Molecular basis of third law. The

    The molecular, or statistical, basis of the third law can be seen by investigating S = k in W.The molecular deductions of the preceding sections have led to the same conclusions as that stated in the third law of thermodynamics, namely, that a value can be

    		•
  • Q : Problem on molality Select the right

    Select the right answer of the question. Calculate the molality of 1 litre solution of 93% H2SO4 (weight/volume). The density of the solution is 1.84 g /ml : (a) 10.43 (b) 20.36 (c) 12.05 (d) 14.05

    		•