--%>
Assignment Help - homework help

What are homogenous catalyst? Give few examples.

When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are:
    
SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst.

2141_homogenous catalyst.png 
    
Oxidization of CO by O2 in the presence of NO as catalyst.

1497_homogenous catalyst1.png 
    
Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst

1588_homogenous catalyst2.png 
    
Hydrolysis of esters using H2SO4 as catalyst

2088_homogenous catalyst3.png 
    
Hydrolysis of sucrose in the presence of dilute sulphuric acid.

84_homogenous catalyst4.png 

Mechanism of homogeneous catalysis 

As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2.
 
In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.

1574_homogenous catalyst5.png

   Related Questions in Chemistry

  • Q : Theory of three dimensional motion

    Partition function; that the translational energy of 1 mol of molecules is 3/2 RT will come as no surprise. But the calculation of this result further illustrates the use of quantized states and the partition function to obtain macroscopic properties. The partition fu

    		•
  • Q : Describe various systems for

    Common system According to this system, the individual members are named according to alkyl groups att

    		•
  • Q : Nuclear Magnetic Resonance The nuclear

    The nuclear states produced by a magnetic field are studied in nuclear magnetic resonance spectroscopy.The frequency of the radiation that corresponds to the nuclear magnetic energy level spacings and the weakness of the radiation absorption that must be e

    		•
  • Q : Base parachloroaniline is strong base

    parachloroaniline is strong base than paranitroaniline

    		•
  • Q : What are haloalkanes and haloarenes and

    Alkyl halides or haloalkanes are the compounds in which a halogen is bonded to an alkyl group. They have the general formula RX (where R is alkyl grou

    		•
  • Q : What are methods of phenol preparation

    Phenol was initially obtained by fractional distillation of coal

    		•
  • Q : How haloalkanes are prepared from

    Alkyl halides can be prepared from alkanes through substitution and from alkenes through addition of halogen acids or through allylic substitution.    From alkanesWhen alkanes are treated with halogens, chlo

    		•
  • Q : Volumes of solution after concentration

    Hydrochloric acid solution A and B encompass concentration of 0.5N and 0.1N  corresspondingly. The volumes of solutions A and B needed to make 2liters of 0.2N of HCL are: (i) 0.5l of A + 1.5l of B (ii) 1.5l of A + 0.5 l of B  (iii) 1.0 l of A + 1.0l of B&nbs

    		•
  • Q : Normality of acetic acid Give me answer

    Give me answer of this question. The normality of 10% (weight/volume) acetic acid is: (a)1 N (b)10 N (c)1.7 N (d) 0.83 N

    		•
  • Q : Haloalkene with the help of polarity of

    with the help of polarity of c-x bond show that aryl halides are less reactive than alkyl halides

    		•