--%>
Assignment Help - homework help

What are homogenous catalyst? Give few examples.

When a catalyst mixes homogeneously with the reactants and forms a single phase, the catalyst is said to be homogeneous and this type of catalysis is called homogeneous catalysis. Some more examples of homogeneous catalysis are:
    
SO2 is oxidized to SO2 in the presence of nitric oxide (NO) as catalyst.

2141_homogenous catalyst.png 
    
Oxidization of CO by O2 in the presence of NO as catalyst.

1497_homogenous catalyst1.png 
    
Preparation of diethyl ether from ethyl alcohol using conc. H2SO4 as catalyst

1588_homogenous catalyst2.png 
    
Hydrolysis of esters using H2SO4 as catalyst

2088_homogenous catalyst3.png 
    
Hydrolysis of sucrose in the presence of dilute sulphuric acid.

84_homogenous catalyst4.png 

Mechanism of homogeneous catalysis 

As pointed out earlier, the catalyst combines with one of the reactant to form some intermediate compound. The intermediate compounds being unstable decompose or combine with each other reacting species to regenerate the catalyst along with the formation of final products. Let us understand the catalytic action of NO in the oxidation of SO2.
 
In this reaction, NO (the catalyst) combines with oxygen to form NO2 (intermediate). The intermediate is consumed in the next step and the catalyst is regenerated.

1574_homogenous catalyst5.png

   Related Questions in Chemistry

  • Q : Units of Measurement Unit of

      Unit of measurement- These are also some systems for units:      (1) 

    		•
  • Q : Calculating molarity of a solution

    Select the right answer of the question .The molarity of a 0.2 N N2Co3 solution will be: (a) 0.05 M (b) 0.2 M (c) 0.1 M (d)0.4 M

    		•
  • Q : Relative lowering of vapour pressure

    Which of the following solutions will have a lower vapour pressure and why? a) A 5% aqueous solution of cane sugar. b) A 5% aqueous solution of urea.

    		•
  • Q : Oxoacids of halogens Why oxidising

    Why oxidising character of oxoacids of halogens decreases as oxidation number increases?

    		•
  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b

    		•
  • Q : Molecular weight of solute Select right

    Select right answer of the question. A dry air is passed through the solution, containing the 10 gm of solute and 90 gm of water and then it pass through pure water. There is the depression in weight of solution wt by 2.5 gm and in weight of pure solvent by 0.05 gm. C

    		•
  • Q : Theory of one dimensional motion For

    For motion in one dimension, the distribution of the molecules over quantum states, speeds, and energies can be deduced.Here we show that the energy of a macroscopic gas sample can be described on the basis of our knowledge of the quantum states allowed to

    		•
  • Q : Schrodinger equation with particle in a

    Three dimensional applications of the Schrodinger equation are introduced by the particle-in-a-box problem.So far only a one-dimensional problem has been solved by application of the Schrodinger equation. Now the allowed energies and the probability functi

    		•
  • Q : Problem on mole fraction of glucose

    Provide solution of this question. While 1.80gm glucose dissolve in 90 of H2O , the mole fraction of glucose is: (a) 0.00399 (b) 0.00199 (c) 0.0199 (d) 0.998

    		•
  • Q : Isotonic Solutions Which one of the

    Which one of the following pairs of solutions can we expect to be isotonic at the same temperature:(i) 0.1M Urea and 0.1M Nacl  (ii) 0.1M Urea and 0.2M Mgcl2  (iii) 0.1M Nacl and 0.1M Na2SO4  (iv) 0.1M Ca(NO3<

    		•