Reversible and irreversible processes in thermodynamics


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Thermodynamics & Newton's law of cooling

Q: Distinguish between reversible and irreversible processes in thermodynamics. Describe the circumstances under which a) dQ = Tds and dW = -PdV.

A long cylinderical rod of radius R is attached to a source of heat at one end and its surroundings are at temperature Ro. Show that at time t, temperature of the rod T(x,t) obeys the given equation (see attachment).

514_eqq.JPG

Assuming from Newton's law of cooling that R(T) = A(T - To) where A is a constant,

a) Obtain an expression for steady state temperature distribution T(x) when hot end of the bar is at temperature T1.

b) Given that A is independent of r, show that in steady state the heat transported away from the hot end is proportional to r^(3/2).

c) Given that the heat loss is negligible (A = 0), show that a solution of the equation is as given

find an expression for a constant γ1157_eqq1.JPG

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Chemistry: Reversible and irreversible processes in thermodynamics
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