Problem on the maxwell boltzmann expression


Response to the following problem:

In the case of N distinguishable particles, the number of ways Ω, in which a macro state defined by N, particles in gl quantum states with energy ?l, N2 particles in g2 quantum states with energy ?2, ... , may be achieved, is given by the Maxwell Boltzmann expression

ΩBE = N!(g1N1 g2N2.../ N1!N2!...) ,

when gi » ni

(a) Using the Stirling approximation, calculate In Ω.

(b) Render In Ω a maximum, subject to the equations of constraint ∑Ni = N = const.and ∑Ni?i = U = const, and explain why U and P should be the same as for indistinguishable particles, but S should be different.

 

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Physics: Problem on the maxwell boltzmann expression
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