Problem on le chateliers principle


Assignment:

Question 1. Bromine water is initially yellow/brown but changes to yellow when sodium hydroxide is added. Then when sulfuric acid is added the solution turns yellow/brown again.
What is happening? Note: Br2(aq) + H2O(l) <----> HOBr2(aq) + Br2 -(aq) + H+

Question 2. Potassium chromate is initially yellow. When sulfuric acid is added the solution turns orange. Then when sodium hydroxide is added the solution turned back yellow.
What is happening? Note: CrO4 2-(aq) + 2H+(aq) <-----> Cr2O7 2-(aq) + H2O(aq)

Question 3. Ethyl acetoacetate and water are clear initially, then when iron(III) chloride is added the solution turned deep purple. Then when bromine water was added the solution turned clear. Over time the deep purple color reappeared in the solution.

What is happening? Note: Ethyl acetate exists as an equilibrium mixture of two forms(called tautomers) -when iron(III) chloride is added to ethylaccetoacetate the solution becomes coloured because of a reaction between the enol form and the iron(III) chloride. The enol form of ethylacetoacetate also reacts with bromine water.

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Chemistry: Problem on le chateliers principle
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