Discuss a thermodynamic relation


Discuss the below:

Apply the thermodynamic relation TdS =dE+pdV to a photon gas. Here one can write that E = Vu where u(T), the mean energy density of the radiation field, is independent of the volume V. The radiation pressure p =u/3

(a) Considering S as a function of T and V, express dS in terms of dT and dV. Find (∂S/∂T)v and (∂s/∂m)T

(b) Show that the mathematical identity (∂2s/∂V∂T)= (∂2s/∂T∂V)gives immediately a differential equation for u which can be integrated to yield the bolzman law u ∝ T4

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Chemistry: Discuss a thermodynamic relation
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