--%>
Assignment Help - homework help

What are aliphatic amines and its nomenclature?

In common system, the aliphatic amines are named by using prefix for alkyl group followed by the word amine.

In case of mixed amines, the name of alkyl groups are arranged in alphabetical order. This is followed by the word amine. However, for simple secondary or tertiary amines another prefix di or tri is added before the name of the alkyl group.

There is yet another system of naming amines according to which they are called aminoalkanes. In this system, the secondary or tertiary amines are named as N-alkylaminoalkanes. In this case, the smaller alkyl groups are taken as subsequent on nitrogen atom of primary amine. For example,

1264_aliphatic amines.png  

In IUPAC system, the amines are considered to be amino derivatives of corresponding alkanes. Therefore, they are called alkanamines. These names are obtained by replacing e from the name of the parent alkane with suffix amine. The secondary and tertiary amines are, however, named as N-substituted derivatives of largest group of primary amines, i.e. N-Alkylalkanamines. The common and IUPAC names of some simple amines are given below in tabular form.

Amine Common Name IUPAC Name
1° Amines    
CH3NH3 Methyl amine Methanamine
CH3CH2NH2 Ethyl amine Ethanamine
CH3CH2CH2NH2 n-Propyl amine Propan-1-amine
(CH3)2CHNH2 Iso-Propyl amine Propan-2-amine
2° Amines    
CH3 - NH - CH3 Dimethyl amine N-Methyl-methanamine
CH3 - NH - C2H5 Ethyl methyl amine N-Methyl-ethanamine
3° Amines    
1097_aliphatic amines1.png Tri-methyl amine N, N-Dimethyl-methanamine
1944_aliphatic amines2.png Ethyl methyl amine N-Ethyl-N-methyl-propanamine
    
For compounds containing more than one amino group, a prefix di, tri, etc. is added before the suffix amine and the terminal e of the name of the hydrocarbon part is retained.

1616_aliphatic amines3.png  

 

 

 

 

 

   Related Questions in Chemistry

  • Q : Liquid Vapour Free Energies The free

    The free energy of a component of a liquid solution is equal to its free energy in the equilibrium vapour.Partial molal free energies let us deal with the free energy of the components of a solution. We use these free energies, or simpler concentration ter

    		•
  • Q : Problem on solutions The 2N aqueous

    The 2N aqueous solution of H2S04 contains: (a) 49 gm of H2S04 per litre of solution (b) 4.9 gm of H2S04 per litre of solution (c) 98 gm of H2S04

    		•
  • Q : Dipole attractions for london dispersion

    Illustrate how are dipole attractions London dispersion forces and hydrogen bonding similar?

    		•
  • Q : What is protein in Chemistry Illustrate

    Illustrate what is protein in Chemistry?

    		•
  • Q : Reason for medications contain hcl What

    What is the reason behind this that some medications contain hcl?

    		•
  • Q : Question on colligative property Choose

    Choose the right answer from following. Which of the following is a colligative property: (a) Osmotic pressure (b) Boiling point (c) Vapour pressure (d) Freezing point

    		•
  • Q : Various cons of eating the organic foods

    Describe the various cons of eating the organic foods? Briefly illustrate it.

    		•
  • Q : Infrared Adsorption The adsorption of

    The adsorption of infrared radiation by diatomic molecules increases the vibrational energy fo molecules and gives information about the force constant for the "spring" of the molecule.;The molecular motion that has the next larger energy level spacing aft

    		•
  • Q : Microwave Adsorption The absorption of

    The absorption of microwave radiation increases the rotational energy of molecules and gives information about the moment of inertia of the molecules.Now we can begin the study of the spectroscopy that explores the different ways in which the energy of the

    		•
  • Q : Problem based on molarity Select the

    Select the right answer of the question. If 18 gm of glucose (C6H12O6) is present in 1000 gm of an aqueous solution of glucose, it is said to be: (a)1 molal (b)1.1 molal (c)0.5 molal (d)0.1 molal

    		•