--%>

Explain the catalyst definition and process with examples.

Catalyst is a substance which accelerates the rate of a chemical reaction without undergoing any change in its chemical composition or mass during the reaction. The phenomenon of increasing the rate of a reaction with the help of a catalyst is known as catalysis.

For example, decomposition of potassium chlorate to give dioxygen occurs at high temperature in the range of 653 - 873 K
                                                      
2KClO3  2458_enzyme catalysis3.png  2KCl + 3O2

However, if a small amount of MnO2 is added to KClO3, its decomposition becomes faster and occurs at lower temperature range 473 - 633 K. the mass and chemical composition of MnO2 remains unaltered at the end of reaction. Thus, MnO2 acts as catalyst for the decomposition of KClO3.

Catalytic action

Since the catalysts are not consumed during the reaction, therefore, only a small amount of catalyst is sufficient to catalyse the reaction. According to modern views, a catalyst speeds up the reaction by providing an alternate path of lower activation energy to the reactants. The catalyst lowers the activation energy by interacting with the reactants leading to the formation of some intermediate complex of lower potential energy. In due course, the intermediate complex decomposes to give the products and also the catalyst.

Promotors and poisons

Promotors are the substances which enhance the activity of catalysts. For example, in the Hber's process for the manufacture of ammonia, molybdenum (Mo) is used as promoter which increases the activity of iron (Fe) used as catalyst
                                              
2218_catalysis.png  

Poisons are the substances which decrease the activity of catalyst. For example, during the Rosemnud's reaction involving the hydrogenation of acetyl chloride, Pd is used as catalyst while BaSO4/quinoline acts as poison. This activity of catalyst is purposely decreased to check the reduction of RCOCl to RCHO stage. If this is not done the desired compound RCHO will further undergo reduction to form alcohol RCH2OH.
                                           
1558_catalysis1.png

   Related Questions in Chemistry

  • Q : Acid Solutions Choose the right answer

    Choose the right answer from following. Volume of water needed to mix with 10 ml 10N NHO3 to get 0.1 N HNO3: (a) 1000 ml (b) 990 ml (c) 1010 ml (d) 10 ml

  • Q : Problem related to molality Help me to

    Help me to solve this problem. What is the molality of a solution which contains 18 g of glucose (C6,H12, O6) in 250 g of water:  (a) 4.0 m (b) 0.4 m (c) 4.2 m (d) 0.8 m

  • Q : Influence of temperature Can someone

    Can someone please help me in getting through this problem. With increase of temperature, which of the following changes: (i) Molality (ii) Weight fraction of solute (iii) Fraction of solute present in water (iv) Mole fraction.

  • Q : Mole fraction of hydrogen Give me

    Give me answer of this question. In a mixture of 1 gm H2 and 8 gm O2 , the mole fraction of hydrogen is: (a) 0.667 (b) 0.5 (c) 0.33 (d) None of these

  • Q : Chem Explain how dissolving the Group

    Explain how dissolving the Group IV carbonate precipitate with 6M CH3COOH, followed by the addition of extra acetic acid.

  • Q : Question relatede to calculate molarity

    Select the right answer of the question. What is molarity of a solution of HCl that contains 49% by weight of solute and whose specific gravity is 1.41 : (a) 15.25 (b) 16.75 (c) 18.92 (d) 20.08

  • Q : Finding strength of HCL solution Can

    Can someone please help me in getting through this problem. 1.0 gm of pure calcium carbonate was found to require 50 ml of dilute  HCL for complete reaction. The strength of the HCL  solution is given by: (a) 4 N  (b) 2 N  (c) 0.4 N  (d) 0.2 N

  • Q : Chemical formula of detergent Describe

    Describe the chemical formula of detergent?

  • Q : Solution and colligative properties

    what is molarity of a solution of hcl which contains 49% by weight of solute and whose specific gravity is 1.41

  • Q : How molecule-molecule collisions takes

    An extension of the kinetic molecular theory of gases recognizes that molecules have an appreciable size and deals with molecule-molecule collisions. We begin studies of elementary reactions by investigating the collisions b