--%>
Assignment Help - homework help

Problem on Clausius-Clapeyron equation

The Clausius-Clapeyron equation gives us an expression for dP/dT. Now we will derive an analog to the Clausius-Clapeyron equation by obtaining an expression for dT/dµ when two phases are at equilibrium. For simplicity, let’s derive this for vapor-liquid (V-L) equilibrium.

a. Write three conditions for V-L equilibrium.
 
b. Obtain an expression for dP in terms of dT and dµ.
 
c. Combine (some) of your results from part (a) and your result from part (b) to find an expression for dT/dµ in terms of T, ρL, ρV (ρ = N/V), SL/VL and SV/VV.

   Related Questions in Chemical Engineering

  • Q : Calculating flow rate of nitrogen The

    The feed of an ammonia synthesis reactor is 25% (lbmole) nitrogen with the balance hydrogen. The flow rate is 3000 kg/h at 65°C and 95 bar. Calculate the flow rate of nitrogen to the reactor in kg/hr.

    		•
  • Q : Problem on heat of sublimation Using

    Using the vapor pressure data provided below, estimatei) the heat of sublimation of ice,ii) the heat of vaporization of water,iii) the heat of fusion of ice and compare your estimate with the published value of 6010 J/moLiv) the triple point of wate

    		•
  • Q : How to balance Chemical Reaction

    Consider a chemical reaction: a CH3-CH=CH2 + b NH3 + c O2 → d CH2=CH-C≡N + e H2O 1.  &

    		•
  • Q : I need to solve the material and energy

    I need to solve the material and energy balance for the att.

    		•
  • Q : Problem on flow rate of natural gas

    Natural Gas is flowing through a 10 inch schedule 40 pipe. The gas is at 109°F and 7.3 psig. The outside air temperature is 92°F. If the flow rate of the gas is 8,000 SCFM: What is the flow rate in lb/hr?

    		•
  • Q : Problem on steam flow in a pipe A

    A stream of steam at 15 bar and 300 oC is used to produce work using a steam turbine. a. Before the turbine, steam flows in a pipe (4 cm in diameter) at a mass flow rate of 3 g/s. Calculate the mean velocity in the pipe

    		•
  • Q : Problem on laboratory solution You are

    You are asked to make up a laboratory solution of 0.10 molar H2SO4 from concentrated (96%) H2SO4 at 56°F. The barometric pressure reads 750 mmHg. You look up the specific gravity of 96% H2SO4 and find it is listed at 1.858. Calculate: (a) th

    		•
  • Q : Draw a flow diagram and annotate the

    Cumene is produced by the vapour phase reaction of benzene with propylene. The fresh feeds have the following compositions: Benzene: 99% w/w benzene, 1% w/w toluene Propylene: 98% v/v propylene,

    		•
  • Q : Thermodynamics I) Sulphur dioxide (SO2)

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may assume ideal gas behaviour. For SO2 take the heat capacity at constant pressure to be CP/R = 3.267+5

    		•
  • Q : Hh to determine the temperature that

    to determine the temperature that occurred in a fire in a warehouse, the arson investigator noticed that the relief valve on a methane storage tank had popped open at 3000 psig, the rated value. Before the fire started, the tank was presumably at ambient conditions and the gage read 1950 psig. If th

    		•