--%>

Problem on Clausius-Clapeyron equation

The Clausius-Clapeyron equation gives us an expression for dP/dT. Now we will derive an analog to the Clausius-Clapeyron equation by obtaining an expression for dT/dµ when two phases are at equilibrium. For simplicity, let’s derive this for vapor-liquid (V-L) equilibrium.

a. Write three conditions for V-L equilibrium.
 
b. Obtain an expression for dP in terms of dT and dµ.
 
c. Combine (some) of your results from part (a) and your result from part (b) to find an expression for dT/dµ in terms of T, ρL, ρV (ρ = N/V), SL/VL and SV/VV.

   Related Questions in Chemical Engineering

  • Q : Problem on molar flow rate I) Sulphur

    I) Sulphur dioxide (SO2) with a volumetric flow rate 5000cm3/s at 1 bar and 1000C is mixed with a second SO2 stream flowing at 2500cm3/s at 2 bar and 200C. The process occurs at steady state. You may as

  • Q : Calculating flow rate of nitrogen The

    The feed of an ammonia synthesis reactor is 25% (lbmole) nitrogen with the balance hydrogen. The flow rate is 3000 kg/h at 65°C and 95 bar. Calculate the flow rate of nitrogen to the reactor in kg/hr.

  • Q : Calculate the pressure Calculate the

    Calculate the pressure at the bottom of a column of Ethanol 100 ft high using a pressure (force) balance in American Engineering Units.

  • Q : Problem on empirical van Laar equation

    At atmospheric pressure ethyl acetate and ethyl alcohol form an azeotropic mixture containing 53.9% mole of ethyl acetate and boiling at 71.8°C. a) Estimate the values of A & B in the empirical van Laar equation

  • Q : Problem on heat required for process A

    A steady-state flow process is used to heat methanol in a tank. The incoming stream is at 2 bar and 25 oC and has a flow rate of 5 kg/s. The outgoing stream is at 1 bar, 100 oC. Heating is provided by a heating coil immersed in a tank. Given the

  • Q : Temprature To determine the temperature

    To determine the temperature that occurred in a ?re in a warehouse, the arson investigator noticed that the relief valve on a methane storage tank had popped open at 3000 psig, the rated value. Before the ?re started, the tank was presumably at ambient conditions and the gage read 1950 psig. If

  • Q : Problem on steam flow in a pipe A

    A stream of steam at 15 bar and 300 oC is used to produce work using a steam turbine. a. Before the turbine, steam flows in a pipe (4 cm in diameter) at a mass flow rate of 3 g/s. Calculate the mean velocity in the pipe

  • Q : Problem on frictional losses A stream

    A stream of propane is throttled from 4.298 bar and 450 K to 0.22 bar. This process is irreversible due to frictional losses at the nozzle. a. In words or equations, why are frictional losses irreversible?

    Q : I need to solve the material and energy

    I need to solve the material and energy balance for the att.

  • Q : Estimating solubility of oxygen in water

    The Henry's law constant for oxygen in water is as follows: Temperature, °C                     0              &nbs