What is the freezing point in the given solutions

What is the freezing point in (C) the solutions below? For water, Kf=1.86 (Ckg)/mol. The vapor pressure of water at 45.0 C is 71.93mm Hg.

1. A solution of 12.5 g of urea, CH4N2O, in 135 g of water at 45 C.

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Chemistry: What is the freezing point in the given solutions
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