--%>
Assignment Help - homework help

Collision & Transition State Theory Homework


Assuming ideal gas: a)  Calculate the average velocity of a nitrogen molecule at 298K and compare to the velocity of a helium molecule at the same conditions.

b)      Calculate the temperature where the velocity of a nitrogen molecule will be the same as that of a helium molecule at 298K.

2. Assuming 1 mol of ideal gas at 100 °C and 1 atm. total pressure and a collision time of 10-13 seconds:

a)      Calculate the total collision number for O2 molecules.  Estimate the molecular diameter for O2 using ChemSketch.

b)      Calculate the total collision number for a mixture of O2 and O4 molecules.  Use a molecular diameter of 4 Å for O4 complexes and assume that all O2-O2 collisions result in the formation of one O4 complex.

a)      What can be concluded regarding the relative likelihood of 2-body interactions (O2-O2) as compared to 3-body interactions (O2-O4)?

 

3. The decomposition of HI:

 

2HI - > I2 + H2

has an experimentally-determined rate constant at 321.4 °C and 1.0 atm of k = 2.0x10-6 l/gmol-s

From collision theory, estimate the rate constant for this reaction and compare to the experimental value.  Assume the steric factor (p) is equal to unity and the activation energy for the reaction is Ea=44 Kcal/gmol. Estimate σAA using ChemSketch.

 

4.  The reaction between atomic and molecular hydrogen proceeds via a linear symmetrical transition state (H3):

H + H2 < -> (H3 ) -> H2+H

Compute the frequency factor (pre-exponential) for this reaction at 300K using transition state theory.

Data:

Moment of inertia (H3) = 3.34x10-40 g-cm2

Moment of inertia (H2) = estimate using ChemSketch

Fundamental vibrational frequency (H2) @ 4395.2 cm-1

Fundamental Frequencies, H3

                Stretching @ 3650 cm-1

                Doubly degenerate bending @ 670 cm-1 

  σ (O2) = 2.636 Å

 σAA = 3.47 Å

 I (H2) = 4.2X10-41 g-cm2

   Related Questions in Physics

  • Q : Brief note on the classification of

    Write down a brief note on the classification of Alloys?

    		•
  • Q : Define Rayleigh criterion or resolving

    Rayleigh criterion: resolving power: The criterion for determining how delicately a set of optics might be able to differentiate. This  starts with the supposition that central ring of one image must fall on the first dark ring of the other; for

    		•
  • Q : Engineering in brief Define the term

    Define the term engineering in brief.

    		•
  • Q : What is Super fluidity Super fluidity :

    Super fluidity: The phenomenon by which, at adequately low temperatures, a fluid can flow with zero (0) viscosity. These causes are related with the superconductivity.

    		•
  • Q : Explain Thomson experiment or Kelvin

    Thomson experiment: Kelvin effect (Sir W. Thomson [later Lord Kelvin]): Whenever an electric current flows via a conductor whose ends are maintained at various temperatures, heat is discharged at a rate just about proportional to the

    		•
  • Q : Problem on multi level TDM Ten sources,

    Ten sources, six with a bit rate of 200 Kbps and four with a bit rate of 400Kbps are to be combined using multi level TDM  with no sync bits. Answer the questions below about the final phase of multiplexing: a

    		•
  • Q : Why Cadmium rods are given in a nuclear

    Cadmium rods are given in a nuclear reactor. Explain why?

    		•
  • Q : Define Centrifugal pseudo force

    Centrifugal pseudo force: A pseudo force which takes place whenever one is moving in uniform circular motion. One feels a "force" directed outward from the center of the motion.

    		•
  • Q : Problem on beam For the beam

    For the beam illustrated below, we require to determine: (A) the support reactions

    		•
  • Q : Explain Fizeau method Fizeau method (A.

    Fizeau method (A. Fizeau, 1851): One of the primary truthfully relativistic experiments intended to compute the speed of light. Light is passed via a spinning cog-wheel driven by running water, is reflected off a far-away mirror, and

    		•